133074-84-7

Basic information

• Product Name: Trifluoro-methanesulfonic acid (3aS,5R,6S,6aS)-5-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester
• Synonyms: Trifluoro-methanesulfonic acid (3aS,5R,6S,6aS)-5-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester
• CAS NO: 133074-84-7
• Molecular Weight: 560.664
• Mol File: 133074-84-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Trifluoro-methanesulfonic acid (3aS,5R,6S,6aS)-5-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Trifluoro-methanesulfonic acid (3aS,5R,6S,6aS)-5-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester(133074-84-7)
• EPA Substance Registry System: Trifluoro-methanesulfonic acid (3aS,5R,6S,6aS)-5-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester(133074-84-7)

Safety Data

• Hazardous Substances Data: 133074-84-7(Hazardous Substances Data)

Upstream product

• 358-23-6 trifluoromethylsulfonic anhydride 
• 133048-89-2 5-O-tert-butyldiphenylsilyl-1,2-O-isopropylidene-β-D-lyxofuranose 
• 172751-32-5 5-O-(tert-butyldiphenylsilyl)-1,2-O-isopropylidene-β-D-threo-pentofuranose-3-ulose 
• 114738-04-4 (3aS,5R,6R,6aS)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-6-ol 
• 168608-39-7 (3S,4S,5R)-5-(((tert-butyldiphenylsilyl)oxy)methyl)tetrahydrofuran-2,3,4-triol 

Downstream Products

• 1395498-27-7 3-deoxy-1,2-O-isopropylidene-5-O-p-toluenesulfonyl-β-D-threo-pentofuranose 
• 168969-77-5 [(3aS,5S,6aS)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]methoxy-tert-butyl-diphenyl-silane 
• 133048-91-6 Trifluoro-methanesulfonic acid (3S,4R,5S)-4-azido-5-(tert-butyl-diphenyl-silanyloxymethyl)-2-oxo-tetrahydro-furan-3-yl ester 
• 133048-86-9 (3S,4S,5S)-4-Azido-5-(tert-butyl-diphenyl-silanyloxymethyl)-3-hydroxy-dihydro-furan-2-one 
• 133048-95-0 Trifluoro-methanesulfonic acid (S)-5-benzyloxymethyl-2-oxo-2,5-dihydro-furan-3-yl ester 
• 89747-12-6 (3aS,5R,6R,6aR)-5-Benzyloxymethyl-6-fluoro-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 133048-85-8 (3R,4S,5R)-5-Benzyloxymethyl-4-fluoro-3-hydroxy-dihydro-furan-2-one 
• 133048-90-5 ((3aS,5S,6R,6aS)-6-Azido-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-ylmethoxy)-tert-butyl-diphenyl-silane 

Relevant articles and documents

Deoxygenation at the C3 position of d- and l-arabinofuranose: Stereospecific access to enantiomeric cordycepose derivatives

Efficient synthesis of 3-deoxy-1,2-O-isopropylidene-β-d- and β-l-threo-pentofuranose (1,2-O-isopropylidene-β-d- and β-l-cordycepose) was accomplished starting from d- and l-arabinofuranose derivatives, respectively, by the action of LiBH(Et)3 on corresponding intermediate 3-O-lyxofuranosyl trifluoromethanesulfonates.