133162-49-9

Upstream product

• 132360-45-3 3,4,5-tri-O-benzyl-1,2-O-cyclohexylidene-6-O-para-methoxybenzyl-D(L)-myo-inositol 
• 23393-20-6 (+/-)-3-O-benzyl-1,2:4,5-di-O,O-cyclohexylidene-myo-inositol 
• 133076-47-8 C₄₅H₅₈O₈ 
• 100-39-0 benzyl bromide 
• 13035-66-0 L-3,4-di-O-benzyl-1,2-O-cyclohexylidene-chiro-inositol 
• 132405-98-2 3,4,5-tri-O-benzyl-1,2-O-cyclohexylidene-D(L)-myo-inositol 
• 170555-90-5 1D-3-O-benzyl-1,2:4,5-di-O-cyclohexylidene-6-O-(4-methoxybenzyl)-myo-inositol 
• 170555-91-6 1D-3-O-benzyl-1,2-O-cyclohexylidene-6-O-(4-methoxybenzyl)-myo-inositol 
• 23393-20-6 1D-3-O-benzyl-1,2:4,5-di-O-cyclohexylidene-myo-inositol 
• 143617-31-6 D-1,2-O-(L-1,7,7-trimethyl<2.2.1>bicyclohept-2-ylidene)-myo-inositol 
• 87-89-8 D-myo-inositol 
• 108-94-1 cyclohexanone 
• 132360-43-1 3-O-benzyl-1,2:4,5-di-O-cyclohexylidene-6-O-para-methoxybenzyl-D(L)-myo-inositol 
• 132360-44-2 3-O-benzyl-1,2-O-cyclohexylidene-6-O-para-methoxybenzyl-D(L)-myo-inositol 

Downstream Products

• 133076-47-8 C₄₅H₅₈O₈ 
• 133076-47-8 C₄₅H₅₈O₈ 
• 132360-47-5 3,4,5-tri-O-benzyl-1,2-O-cyclohexylidene-6-O-(2'-O-acetyl-3',4',6'-tri-O-benzyl-α-D-mannopyranosyl)-D/L-myo-inositol 
• 133076-45-6 O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->6)-2,3,4,5-tetra-O-benzyl-D-myo-inositol 
• 133076-43-4 (1R,2R,3S,4S,5R,6S)-3-((2R,3R,4R,5S,6R)-3-Azido-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4,5,6-tris-benzyloxy-2-(4-methoxy-benzyloxy)-cyclohexanol 
• 133076-44-5 (2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1-6)-1-O-4-methoxybenzyl-2,3,4,5-tetra-O-benzyl-D-myo-inositol 
• 133163-53-8 O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-1,5,6-tri-O-benzyl-L-myo-inositol 
• 54422-83-2 6-O-(α-D-mannopyranosyl)-D-myo-inositol 
• 132360-49-7 3,4,5-tri-O-benzyl-1,2-O-cyclohexylidene-6-O-(3',4',6'-tri-O-benzyl-α-D-mannopyranosyl)-L-myo-inositol 
• 132437-47-9 3,4,5-tri-O-benzyl-1,2-O-cyclohexylidene-6-O-(3',4',6'-tri-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol 
• 132360-51-1 3,4,5-tri-O-benzyl-6-O-(2',3',4',6'-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol 
• 132360-51-1 3,4,5-tri-O-benzyl-6-O-(2',3',4',6'-tetra-O-benzyl-α-D-mannopyranosyl)-L-myo-inositol 
• 132360-52-2 1-O-allyl-3,4,5-tri-O-benzyl-6-O-(2',3',4',6'-tetra-O-benzyl-α-D-mannopyranosyl)-L-myo-inositol 
• 132360-52-2 1-O-allyl-3,4,5-tri-O-benzyl-6-O-(2',3',4',6'-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol 

Relevant academic research and scientific papers

Efficient routes to glucosamine-myo-inositol derivatives, key building blocks in the synthesis of glycosylphosphatidylinositol anchor substances

Short synthetic routes to protected derivatives of 2-amino-2-deoxy-α-D-glucopyranosyl-(1→6)-D-myo-inositol are described. Various 2-azido-2-deoxy-glucosyl donors were synthesized, starting from D-glucal or glucosamine hydrochloride. Derivatives of 1,2- and 2,3- D-myo-inositol-camphanylidene acetals were prepared to function as glycosyl acceptors. The subsequent glycosylations produced useful building blocks for the synthesis of GPI-anchor substances.

Synthesis of a partially protected 1D-6-O-(2-azido-2-deoxy-α-D-glucopyranosyl)-myo-inositol: a useful precursor of glycosylphosphatidylinositols and related compounds

GPI anchors; Glycosylphosphatidylinositol precursor; 1D-6-O-(2-Azido-2-deoxy-α-D-glucopyranosyl)-myo-inositol; 1D-myo-Inositol derivatives

STEREOSPECIFIC SYNTHESIS OF PARTIALLY PROTECTED 2-AZIDO-2-DEOXY-D-GLUCOSYL D-MYO-INOSITOL: PRECURSOR OF A POTENTIAL INSULIN MIMETIC AND MEMBRANE PROTEIN ANCHORING SITE

Racemic and partially protected myo-inositol derivative 5 was coupled stereospecifically with the 2-azido-2-deoxy-glucosyl trichloroacetimidate donor 8.Optical resolution of the thus obtained diastereoisomeric mixture of dimers by silica gel column chromatography, and further protective group manipulations, afforded the suitably protected title compound 14.

THE PREPARATION OF CYCLOHEXANEPENTOLS FROM INOSITOLS BY DEOXYGENATION

Several cyclohexapenetols heva been synthesized from inositols by blocking all but one hydroxyl group, converting the free hydroxyl group into its S-methyl dithiocarbonate, and treating it with tributylstannane.Suitable blocking-groups are methyl, benzyl, and methylthiomethyl ethers, and acetals.One cyclohexanepentol was prepared by the reductive deamination of an aminodeoxyinositol.