133181-66-5Relevant academic research and scientific papers
Chiral ligands containing heteroatoms.7. An investigation on the stereochemistry of the ketone reductions by chiral diamines/tin hydride systems
Falorni,Giacomelli,Marchetti,Culeddu,Lardicci
, p. 287 - 298 (1991)
Reducing agents prepared from SnCl2, chiral diamines and diisobutyl aluminum hydride have been applied to the enantioselective reduction of alkyl phenyl and α-alkynyl ketones. The extent of the ee observed was dependent on the hydrolysis temper
CHIRAL LIGANDS CONTAINING HETEROATOMS. V ENANTIOSELECTIVE KETONE REDUCTION USING CHIRAL DIAMINES/METAL HYDRIDE SYSTEMS
Falorni, Massimo,Giacomelli, Giampaolo,Lardicci, Luciano
, p. 765 - 769 (2007/10/02)
New chiral reducing agents prepared from zinc or magnesium dichloride, optically active diamines and diisobutylaluminium hydride, have been studied.These complexes were used in the reduction of a series of prochiral ketones and, compared with similar tin(
