133359-89-4

Upstream product

• 132164-16-0 (2R,S_S)-(-)-1-chloro-1,1-difluoro-3-(p-tolylsulphinyl)propan-2-ol 
• 106-95-6 allyl bromide 

Downstream Products

• 133343-62-1 1-((R)-2-Allyloxy-3-chloro-3,3-difluoro-propylsulfanyl)-4-methyl-benzene 
• 133442-64-5 (2S,4R)-3,3-Difluoro-4-methyl-2-((S)-toluene-4-sulfinylmethyl)-tetrahydro-furan 
• 133442-63-4 (2S,4S)-3,3-Difluoro-4-methyl-2-((S)-toluene-4-sulfinylmethyl)-tetrahydro-furan 
• 136848-13-0 1-((R)-2-Allyloxy-3-chloro-3,3-difluoro-propane-1-sulfonyl)-4-methyl-benzene 

Relevant academic research and scientific papers

Intramolecular trapping of difluoroalkyl radicals by tethered olefin in the asymmetric synthesis of 2,4-disubstituted-3,3-difluorotetrahydrofurans

Optically pure propenyl ethers of 3-sulphenyl-, 3-sulphuryl-, and 3-sulphonyl-1-chloro-1,1-difluoropropan-2-ols were submitted to radical cyclization affording, with moderate to high diastereoselectivity. 3,3-difluorotetrahydrofurans containing in 2 and 4

NEW CHIRONS FOR THE SYNTHESIS OF FLUORINE-CONTAINING ORGANIC COMPOUNDS. HOMOCHIRAL 3--1,1,1-TRIHALO-PROPAN-2-ONES, -PROPAN-2-OLS AND -PROPAN-2-OL ALKENYL ETHERS

The condensation of the lithium derivative of methyl 4-methylphenyl (S)-(-)-sulphoxide, 1, with ethyl esters of 1-fluoro-, 1-chloro-, 1-chloro-1,1-difluoro-, 1-bromo-1,1-difluoro- and 1,1-dichloro-1-fluoro-acetic acids, 2a-e, respectively, afforded enanti