133371-96-7

Basic information

• Product Name: Piperidine, 2-(2-propenyl)-, (R)- (9CI)
• Synonyms: Piperidine, 2-(2-propenyl)-, (R)- (9CI);(R)- 2-(2-PROPENYL)-PIPERIDINE;(2R)-2-PROP-2-ENYLPIPERIDINE
• CAS NO: 133371-96-7
• Molecular Formula: C8H15N
• Molecular Weight: 125.2114
• Product Categories: PIPERIDINE
• Mol File: 133371-96-7.mol
• Article Data: 13

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Piperidine, 2-(2-propenyl)-, (R)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Piperidine, 2-(2-propenyl)-, (R)- (9CI)(133371-96-7)
• EPA Substance Registry System: Piperidine, 2-(2-propenyl)-, (R)- (9CI)(133371-96-7)

Safety Data

• Hazardous Substances Data: 133371-96-7(Hazardous Substances Data)

Upstream product

• 95683-74-2 3-allyl-2-piperidinone 
• 522-33-8 Tripiperidin 
• 1594-94-1 allyl dimethyl boronic acid ester 
• 201350-80-3 (R)-tert-butyl 2-allylpiperidine-1-carboxylate 
• 184535-03-3 (S)-8-Azido-oct-1-en-4-ol 
• 184535-02-2 (S)-1-azido-5,6-epoxyhexane 
• 184535-01-1 (S)-6-azido-2-hydroxy-1-hexanol 
• 821-77-2 5-hexenylazide 
• 184535-04-4 Methanesulfonic acid (S)-1-allyl-5-azido-pentyl ester 
• 959420-89-4 (+)-(S)-N-[(1E)-5-chloropentylidene]-2-methylpropane-2-sulfinamide 
• 20074-80-0 5-chloro-pentanal 
• 184535-09-9 (S)-2-allyl-piperidine-1-carboxylic acid tert-butyl ester 
• 1214914-47-2 C₂₅H₂₇NO 
• 67-56-1 methanol 

Downstream Products

• 1312812-27-3 (3R,4aS)-3-(chloromethyl)-2-(4-nitrophenyl)octahydro-1H-pyrido[1,2-c]pyrimidin-1-one 
• 1312812-31-9 (3aS,9aS,10aS)-3-(3,5-dichloro-2,4,6-trimethylphenyl)-3a,6,7,8,9,9a,10,10a-octahydroisoxazolo[5,4-b]quinolizin-4-one 
• 1312812-26-2 (3S,4aR)-3-(chloromethyl)-2-(4-nitrophenyl)octahydro-1H-pyrido[1,2-c]pyrimidin-1-one 
• 1312812-30-8 (3aR,9aR,10aR)-3-(3,5-dichloro-2,4,6-trimethylphenyl)-3a,6,7,8,9,9a,10,10a-octahydroisoxazolo[5,4-b]quinolizin-4-one 
• 705282-43-5 1-chloroformyl-2-(2-propenyl)piperidine 
• 491-40-7 quinolizidin-4-one 

Relevant articles and documents

Stereocontrolled synthesis of bicyclic ureas and sulfamides via Pd-catalyzed alkene carboamination reactions

The synthesis of bicyclic ureas and sulfamides via palladium-catalyzed alkene carboamination reactions between aryl/alkenyl halides/triflates and alkenes bearing pendant cyclic sulfamides and ureas is described. The substrates for these reactions are gene

Enantiopure 2-piperidylacetaldehyde as a useful building block in the diversity-oriented synthesis of polycyclic piperidine derivatives

Novel, simple, and convenient strategies for diversely functionalized piperidine derivatives have been developed by using different metal catalyzed reactions starting from enantiopure (R)- and (S)-2-piperidylacetaldehyde.

Preparation of enantiopure substituted piperidines containing 2-alkene or 2-alkyne Chains: Application to total syntheses of natural quinolizidine- alkaloids

"Chemical Equation Presented" A general method, for the preparation of enantiopure 2-alkene- or 2-alkyne-containing chain substituted piperidines was established by using nonracemic Betti base as a chiral auxiliary. The key step is that the auxiliary residue was removed by a novel base-catalyzed N-debenzylation via a formation of o-quinone methide mechanism in stead, of the traditional hydrogenolysis, by which the alkene or alkyne groups survived. By this method, ten 2-alkene- or 2-alkyne-containing chain substituted piperidines were prepared on the gram scale within a few hours. To demonstrate the efficiency of the method and the versatility of the product, total, syntheses of natural alkaloids (+)-pelletierine((-)-lasubine II, and (-)-cermizine C were achieved by using (S)-2-allyl-N-Bocpiperidine as a versatile building block.