133379-85-8

Basic information

• Product Name: methyl (2S*,3R*)-2--3-methoxy-3-phenylpropanoate
• CAS NO: 133379-85-8
• Molecular Weight: 234.295
• Mol File: 133379-85-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl (2S*,3R*)-2--3-methoxy-3-phenylpropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (2S*,3R*)-2--3-methoxy-3-phenylpropanoate(133379-85-8)
• EPA Substance Registry System: methyl (2S*,3R*)-2--3-methoxy-3-phenylpropanoate(133379-85-8)

Safety Data

• Hazardous Substances Data: 133379-85-8(Hazardous Substances Data)

Upstream product

• 19713-73-6 methyl (2Z)-3-phenylprop-2-enoate 
• 762-72-1 allyl-trimethyl-silane 
• 52742-05-9 methyl (2S*,3R*)-2-bromo-3-methoxy-3-phenylpropanoate 
• 52742-05-9 methyl (+/-)-(2R,3R)-2-bromo-3-methoxy-3-phenylpropanoate 
• 24850-33-7 allyltributylstanane 
• 93643-71-1 methyl (±)-anti-2-iodo-3-methoxy-3-phenylpropanoate 
• 103-26-4 Methyl cinnamate 

Relevant articles and documents

Stereoselective radical carbon-carbon bond forming reactions of β-alkoxy esters: Atom and group transfer allylations under bidentate chelation controlled conditions

The radical allylation of a series of β-alkoxy esters using allyltrimethylsilane in the presence of MgBr2·OEt2 is described. Under bidentate chelation-controlled conditions, allyltrimethylsilane rivals allyltributyltin in efficiency

Stereoselective rardical-mediated reduction and alkylation of α-halo esters

Radical-mediated reduction and alkylation of β-alkoxy-α-halo esters could be achieved with good stereoselection at low temperature.