133379-85-8Relevant academic research and scientific papers
Stereoselective radical carbon-carbon bond forming reactions of β-alkoxy esters: Atom and group transfer allylations under bidentate chelation controlled conditions
Guindon,Guérin,Chabot,Ogilvie
, p. 12528 - 12535 (2007/10/03)
The radical allylation of a series of β-alkoxy esters using allyltrimethylsilane in the presence of MgBr2·OEt2 is described. Under bidentate chelation-controlled conditions, allyltrimethylsilane rivals allyltributyltin in efficiency
Investigation of a Model for 1,2-Asymmetric Induction in Reactions of α-Carbalkoxy Radicals: A Stereochemical Comparison of Reactions of α-Carbalkoxy Radicals and Ester Enolates
Hart, David J.,Krishnamurthy, Ramanarayanan
, p. 4457 - 4470 (2007/10/02)
The stereochemical course of reductions and allylations of α-carbalkoxy radicals with chiral centers at the β-position are reported.Radicals without polar substituents, with alkoxyl or acetoxyl groups, and with hydroxyl groups at the β-position were exami
Stereoselective rardical-mediated reduction and alkylation of α-halo esters
Guindon,Lavallee,Boisvert,Chabot,Delorme,Yoakim,Hall,Lemieux,Simoneau
, p. 27 - 30 (2007/10/02)
Radical-mediated reduction and alkylation of β-alkoxy-α-halo esters could be achieved with good stereoselection at low temperature.
