93643-71-1Relevant academic research and scientific papers
A new alkoxy-, hydroxy-and nitratoiodination of a,β-unsaturated esters and amides using iodine-ammonium cerium (IV) nitrate and cerium (IV) sulfate
Utsukihara, Takamitsu,Ochiai, Keiko,Koshimura, Masahiro,Hashimoto, Chikao,Fujishiro, Hiroko,Ikeda, Akira,Kanamori, Miyuki,Horiuchi, C. Akira
, p. 1503 - 1510 (2017/11/10)
The reactions of electron-deficient α β-unsaturated esters using I2-ammonium cerium (IV) nitrate (CAN) or I2-cerium (IV) sulfate (CS) in alcohols (methanol, ethanol, or 1-propanol) under 50°C-reflux give the corresponding-β-alkoxy-a-
Comparative study of the vicinal functionalization of olefins with 2:1 bromide/bromate and iodide/iodate reagents
Agrawal, Manoj K.,Adimurthy, Subbarayappa,Ganguly, Bishwajit,Ghosh, Pushpito K.
experimental part, p. 2791 - 2797 (2009/08/08)
A comparative evaluation was made on the syntheses of vicinal halohydrins, halo methyl ethers, and halo acetates from olefins using 2:1 Br-/BrO3- and I-/IO3- reagents. In many cases both reagents afforded products selectively in high yields. The highest halogen atom efficiencies attained were 97% and 93% for Br-/BrO3- and I-/IO3-, respectively. Of the two reagents, I-/IO3- was established to be the preferred reagent for vicinal functionalization of linear alkenes and also for halo acetate preparation. However, only Br-/BrO3- was effective for vicinal functionalization of trans-stilbene and chalcones.
Stereoselective radical carbon-carbon bond forming reactions of β-alkoxy esters: Atom and group transfer allylations under bidentate chelation controlled conditions
Guindon,Guérin,Chabot,Ogilvie
, p. 12528 - 12535 (2007/10/03)
The radical allylation of a series of β-alkoxy esters using allyltrimethylsilane in the presence of MgBr2·OEt2 is described. Under bidentate chelation-controlled conditions, allyltrimethylsilane rivals allyltributyltin in efficiency
Metal Reagents in Organic Reactions: Part IV-Mercuration and Demercuration of Cinnamic Acid and Its Derivatives
Banerji, Avijit,Ghosal, Tapasree
, p. 427 - 430 (2007/10/02)
Methoxy-mercuration of cinnamic acid and methyl cinnamate with mercuric acetate in dry methanol has been carried out and the products identified.Transformation reactions of the mercurated products have been investigated, particularly regarding their behav
