1334500-68-3

Basic information

• Product Name: diisopropyl 1-(2-nitrophenyl)-hydrazine-1,2-dicarboxylate
• Synonyms: diisopropyl 1-(2-nitrophenyl)-hydrazine-1,2-dicarboxylate
• CAS NO: 1334500-68-3
• Molecular Weight: 325.321
• Mol File: 1334500-68-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: diisopropyl 1-(2-nitrophenyl)-hydrazine-1,2-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: diisopropyl 1-(2-nitrophenyl)-hydrazine-1,2-dicarboxylate(1334500-68-3)
• EPA Substance Registry System: diisopropyl 1-(2-nitrophenyl)-hydrazine-1,2-dicarboxylate(1334500-68-3)

Safety Data

• Hazardous Substances Data: 1334500-68-3(Hazardous Substances Data)

Upstream product

• 2446-83-5 di-isopropyl azodicarboxylate 
• 609-73-4 o-nitroiodobenzene 
• 88-74-4 2-nitro-aniline 
• 132993-22-7 2-nitrophenyl trifluoromethanesulfonate 
• 577-19-5 2-nitrophenyl bromide 

Relevant articles and documents

Copper-catalyzed C-N bond formation using dialkyl azodicarboxylate as the amination reagent

An efficient copper-catalyzed reaction for C-N bond formation using aryl halides, dialkyl azodicarboxylate, and a hydride source is reported. Using this procedure, aryl iodides reacted at ambient conditions, while aryl bromides required heating to 60 °C to accomplish the transformation. Various functional groups were tolerated under the optimum conditions.

Sodium hydride induced N-arylation of diisopropyl azodicarboxylate by aryl trifluoromethanesulfonates

A method for intermolecular N-arylation of the anionic species derived from diisopropyl azodicarboxylate and sodium hydride by aryl trifluoromethanesulfonates, in the presence of a ligand-free copper(I) oxide catalyst at 80 °C in N,N-dimethylformamide, is reported. A variety of functionalized aryl triflouromethanesulfonates were efficiently coupled by this method.