1334715-07-9Relevant academic research and scientific papers
Electronic properties and reactivity of an isolable phosphagermaheterocyclic carbene
Ghereg, Dumitru,Ladeira, Sonia,Saffon, Nathalie,Escudie, Jean,Gornitzka, Heinz
, p. 7607 - 7610 (2011)
A highly reactive phosphagermacarbene (PGeHC) was synthesized by [3+2] cycloaddition between phosphagermaallene Tip(tBu)GeiCiPMes* (Tip= 2,4,6-triisopropylphenyl; Mes=2,4,6-tris-tert-butylphenyl) and diphenylketene. It forms complexes with [{Rh(CO)2Cl}2] and Me3P, and undergoes a Wittig-type reaction with diphenylketene (see scheme). Copyright
