13351-28-5Relevant articles and documents
Titanium(III) Chloride Mediated Reduction of Dicyanoalkenes
Sera, Akira,Tsuzuki, Toshihiro,Satoh, Eishi,Itoh, Kuniaki
, p. 3068 - 3071 (1992)
The reaction of substituted dicyanoalkenes with aqueous titanium(III) chloride was examined.The dicyanoalkenes, which showed irreversible reduction characteristics on cyclic voltammograms, (typically, 2-cyano-3-phenylpropenenitrile), afforded cyclized and
Stereoselectivity and mechanism in the electrohydrodimerisation of esters of cinnamic acid
Fussing, Ingrid,Guellue, Mustafa,Hammerich, Ole,Hussain, Abid,Nielsen, Merete Folmer,Utley, James H. P.
, p. 649 - 658 (2007/10/03)
Rate constants (kobs) and reaction orders have been determined for the cathodic reduction in DMF solution of 11 cinnamiic acid esters including some derived from chiral alcohols and a dicinnamate derived from trans-cyclohexane-1,2-diol.The cinn
Reaction of α-Substituted β-Bromostyrenes with Dicarbonyldicyanonickelate(0) Anion in Alkaline Medium under Carbon Monoxide
Miura, Masahiro,Shimoura, Nobuhiro,Nomura, Masakatsu
, p. 1993 - 1996 (2007/10/02)
The reactions of (E)- and (Z)-β-bromostyrene (1a) with dicarbonyldicyanonickelate(0) anion generated in situ in the presence of sodium or calcium hydroxide under carbon monoxide gave a carbonylated product mixture of (E)-cinnamic acid , 3,4-diphenylhexanedioic acid (4), and 3-phenylpropionic acid (5).In contrast, in the reactions of α-methyl- and phenyl-β-bromostyrenes (1b and c) the corresponding nitriles (3b and c) were formed, together with the carboxylic acids (2b and c).