1335290-15-7Relevant academic research and scientific papers
Thieno[3,2-b]pyrrolo donor fused with benzothiadiazolo, benzoselenadiazolo and quinoxalino acceptors: Synthesis, characterization, and molecular properties
Cheng, Yen-Ju,Chen, Chiu-Hsiang,Ho, Yu-Ju,Chang, Shu-Wei,Witek, Henryk A.,Hsu, Chain-Shu
, p. 5484 - 5487 (2011)
Nitrogen-bridged donor-acceptor multifused dithienopyrrolobenzothiadiazole (DTPBT) and dibenzothiadiazolopyrrolothiophene (DBTPT) were successfully synthesized by intramolecular Cadogan annulation. The electron-deficient benzothiadiazole unit in DTPBT can be converted to benzoselenadiazole and quinoxaline moieties through reduction/cyclization to generate dithienopyrrolobenzoselenadiazole (DTPBSe) and dithienopyrroloquinoxaline (DTPQX), respectively. The nitrogen atoms function as the bridges for covalent planarization to induce intermolecular interaction and intramolecular charge transfer.
