13360-92-4

Basic information

• Product Name: Phenyldiphenylphosphinite(Diphenylphosphinicacidphenylester)
• Synonyms: Phenoxydiphenylphosphine
• CAS NO: 13360-92-4
• Molecular Formula: C₁₈H₁₅OP
• Molecular Weight: 278.289
• Mol File: 13360-92-4.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 170°C/2mmHg(lit.)
• Flash Point: 235.23 °C
• Appearance: /
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.6360 to 1.6400
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• CAS DataBase Reference: Phenyldiphenylphosphinite(Diphenylphosphinicacidphenylester)(CAS DataBase Reference)
• NIST Chemistry Reference: Phenyldiphenylphosphinite(Diphenylphosphinicacidphenylester)(13360-92-4)
• EPA Substance Registry System: Phenyldiphenylphosphinite(Diphenylphosphinicacidphenylester)(13360-92-4)

Safety Data

• Hazardous Substances Data: 13360-92-4(Hazardous Substances Data)

Usage

General Description

Phenyldiphenylphosphinite, also known as diphenylphosphinic acid phenyl ester, is a chemical compound that falls under the category of organophosphorus compounds. It has the chemical formula C18H15O2P. While Phenyldiphenylphosphinite isn’t typically used in mainstream industrial applications due to its specialized nature, it is valuable in specific scientific and research contexts, especially as a reagent in organic synthesis. Detailed information about its physical and chemical properties like molar mass, density, boiling and melting points may vary between sources. Proper precautions must be taken while handling this compound due to associated health risks. As with many chemicals, it is important to source accurate information about its storage, disposal, and potential hazards from verified scientific databases or professionals.

InChI:InChI=1/C18H15OP/c1-4-10-16(11-5-1)19-20(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

Upstream product

• 1079-66-9 chloro-diphenylphosphine 
• 108-95-2 phenol 
• 3426-89-9 phenyl phosphorodichloridite 

Downstream Products

• 4181-97-9 phenyl 4-methoxybenzoate 
• 351874-81-2 α-ethylbenzeneacetic acid phenyl ester 
• 148421-76-5 Au{P(C₆H₅)2(OC₆H₅)}Cl 
• 74587-71-6 trans-RhCl(CO)(phenyl diphenylphosphinite)2 
• 190135-31-0 [PtCl₂(P(C₂H₅)3)(P(C₆H₅)2OC₆H₅)] 
• 51456-47-4 cis-[PdCl₂(PPh₂(OPh))2] 
• 129922-46-9 triphenyl(trifluoromethyl)phosphonium trifluoromethanesulfonate 
• 2129-89-7 diphenyl(methyl)phosphine oxide 
• 16284-64-3 diphenyltrifluoromethylphosphine oxide 
• 791-28-6 Triphenylphosphine oxide 
• 72450-51-2 bis(triphenyl)oxodiphosphonium trifluoromethanesulfonate salt 
• 100600-01-9 phenyl <(18)O>benzoate 
• 5798-76-5 phenyl 4-bromobenzoate 
• 2757-04-2 phenyl cinnamate 

Relevant articles and documents

Palladacyclic phosphinite complexes as extremely high activity catalysts in the Suzuki reaction

Phosphinite based palladacycles show extremely high activity in the Suzuki coupling of both sterically hindered and electronically deactivated aryl bromides, especially in the presence of one equivalent of free ligand.

Chemoselective reduction of the phosphoryl bond of O-alkyl phosphinates and related compounds: An apparently impossible transformation

A method is reported for the phosphoryl bond cleavage of O-alkyl phosphinates, phosphinothioates and certain phosphonamidates to furnish the corresponding P(iii) borane adducts. The two-step procedure relies upon initial activation of the phosphoryl bond with an alkyl triflate, followed by reduction of the resulting intermediate using lithium borohydride.

Conversion of alcohols to alkyl aryl sulfides by a new type of oxidation-reduction condensation using phenyl diphenylphosphinite

Preparation of alkyl aryl sulfides from alcohols and arenethiols such as 2-sulfanyl-1,3-benzothiazole (BtzSH) is described by a new type of oxidation-reduction condensation using phenyl diphenylphosphinite (PhOPPh 2) and benzoquinone derivatives or azide compounds. This reaction proceeds under mild and neutral conditions and is applicable to the thioetherification of various alcohols in which the chiral secondary and tertiary alcohols are converted into the corresponding chiral sulfides with almost complete inversion of configuration.