133620-98-1Relevant academic research and scientific papers
[3+3] Annulation by sequential two electron and one electron allylation
Ward, Dale E.,Kaller, Brian F.
, p. 843 - 846 (2007/10/02)
3-phenylthio-2-(trimethylsilymethyl)propene is a convenient conjunctive reagent for the preparation of methylenecyclohexanes via a [3+3] annulation. The trimethylsilyl group facilitates the Lewis acid catalyzed allylation of an aldehyde or acetal while the phenylthio group directs a 6-endo-trig radical cyclization reaction.
