13370-79-1Relevant articles and documents
A new inorganic–organic nanohybrid based on a copper(II) semicarbazone complex and the PMo12O403?polyanion: Synthesis, characterization, crystal structure and photocatalytic activity for degradation of cationic dyes
Farhadi, Saeed,Mahmoudi, Farzaneh,Dusek, Michal,Eigner, Vaclav,Kucerakova, Monika
, p. 247 - 256 (2017)
A new inorganic–organic nanohybrid based on a Keggin-type polyoxomolybdate and a copper(II) semicarbazone complex, namely [Cu2(HL)2(PMo12O40)(OCH3)2(Cl)(H2O)]·8CH3OH·4H2O [HL = pyridine-2-carbaldehyde semicarbazone] (1) was synthesized by a sonochemical method. Single crystals of 1 were synthesized with the branched tube method. The nanohybrid 1 was characterized using FT-IR, PXRD, FESEM, TEM, EDX, UV–Vis, TG-DTA analysis and single-crystal X-ray diffraction. Single-crystal X-ray diffraction reveals that the PMo12O403?cluster acts as a bidentate inorganic ligand and coordinates two symmetrically equivalent [Cu(Cl)0.5(HL)(OCH3)(H2O)0.5] complexes. SEM and TEM images confirmed a highly porous plate-like morphology of the nanohybrid sample. To the best of our knowledge, 1 represents the first example of a hybrid based on POMs and semicarbazone Schiff base complexes. The photocatalytic properties of the nanohybrid 1 were investigated in detail and the results of the photocatalytic experiments show it can be used as an efficient and recoverable photocatalyst for the complete degradation of the cationic dyes methylene blue (MB) and rhodamin B (RhB).
A new nanohybrid material constructed from Keggin-type polyoxometalate and Cd(II) semicarbazone Schiff base complex with excellent adsorption properties for the removal of cationic dye pollutants
Farhadi, Saeed,Amini, Mostafa M.,Dusek, Michal,Kucerakova, Monika,Mahmoudi, Farzaneh
, p. 592 - 602 (2017)
A novel nanohybrid material containing a Cd(II) semicarbazone Schiff base complex and phosphomolybdic acid, [Cd(H2L+)6][H2L]+4[PMo12O40]4·18CH3OH
Synthesis, crystal structure, antimicrobial activity and electrochemistry study of chromium(III) and copper(II) complexes based on semicarbazone Schiff base and azide ligands
Shaabani,Khandar,Dusek,Pojarova,Mahmoudi
, p. 563 - 568 (2013)
A tridentate NNO donor Schiff base ligand HL [HL: C5H 4NCH=NNHCONH2] was obtained by condensation of pyridine 2-carbaldehyde with semicarbazide. The HL and azide ligands with Cr(III) and Cu(II) ions have been used to synth
Synthesis, characterization and biological activities of semicarbazones and their copper complexes
Venkatachalam, Taracad K.,Bernhardt, Paul V.,Noble, Chris J.,Fletcher, Nicholas,Pierens, Gregory K.,Thurecht, Kris J.,Reutens, David C.
, p. 295 - 308 (2016/11/12)
Substituted semicarbazones/thiosemicarbazones and their copper complexes have been prepared and several single crystal structures examined. The copper complexes of these semicarbazone/thiosemicarbazones were prepared and several crystal structures examined. The single crystal X-ray structure of the pyridyl-substituted semicarbazone showed two types of copper complexes, a monomer and a dimer. We also found that the p-nitrophenyl semicarbazone formed a conventional ‘magic lantern’ acetate-bridged dimer. Electron Paramagnetic Resonance (EPR) of several of the copper complexes was consistent with the results of single crystal X-ray crystallography. The EPR spectra of the p-nitrophenyl semicarbazone copper complex in dimethylsulfoxide (DMSO) showed the presence of two species, confirming the structural information. Since thiosemicarbazones and semicarbazones have been reported to exhibit anticancer activity, we examined the anticancer activity of several of the derivatives reported in the present study and interestingly only the thiosemicarbazone showed activity while the semicarbazones were not active indicating that introduction of sulphur atom alters the biological profile of these thiosemicarbazones.