13383-32-9Relevant articles and documents
Enthalpy versus entropy in chlorocarbene/alkene addition reactions
Moss, Robert A.,Wang, Lei,Zhang, Min,Skalit, Christopher,Krogh-Jespersen, Karsten
, p. 5634 - 5635 (2008)
We report the first measured activation parameters for the additions of CCl2 and CClF to simple alkenes and demonstrate the existence of enthalpic barriers for CCl2 additions to cyclohexene and 1-hexene. With these two alkenes, addit
The reaction of benzotrihalides and benzal halides with magnesium. Synthetic and mechanistic studies
Ashby, E. C.,Al-Fekri, Dheya M.
, p. 275 - 292 (2007/10/02)
The benzotrihalides (PhCX3) where X = Cl, Br, and F were allowed to react with magnesium in THF at room temperature.When the halide was chloride or bromide, the trihalide gave diphenylacetylene in high yield in addition to several minor products which were identified.No reaction was observed when the halide was fluoride.When the corresponding dichloride was allowed to react with magnesium in THF, stilbene was formed as the major product.The possible mechanisms for these reactions are discussed.