13388-33-5Relevant articles and documents
PolyTCAQ in organic batteries: Enhanced capacity at constant cell potential using two-electron-redox-reactions
Haeupler, Bernhard,Burges, Rene,Janoschka, Tobias,Jaehnert, Thomas,Wild, Andreas,Schubert, Ulrich S.
, p. 8999 - 9001 (2014)
The application of polymers bearing tetracyano-9,10-anthraquinonedimethane (TCAQ) units as electrode materials in organic batteries enables one narrow charge discharge plateau due to the one two-electron-redox-reaction of the TCAQ core. Li-organic batteries manufactured with this polymer display repeatable charge-discharge characteristics associated with a capacity of 156 mA h g -1 and a material activity of 97%.
Poly[N-(10-oxo-2-vinylanthracen-9(10H)-ylidene)cyanamide] as a novel cathode material for li-organic batteries
Schmidt, Daniel,H?upler, Bernhard,Stolze, Christian,Hager, Martin D.,Schubert, Ulrich S.
, p. 2517 - 2523 (2015)
Redox-active polymers draw significant attention as active material in secondary batteries during the last decade. A new anthraquinone-based redox-active monomer was designed, which electrochemical behavior was tailored by mono-modification of one keto group. The monomer exhibits two one-electron redox reactions and has a low molar mass, resulting in a high theoretical capacity of 207 mAh/g. The polymerization of the monomer was optimized by variation of solvent and initiator. Moreover, the electrochemical behavior was studied using cyclic voltammetry and the polymer was used as active material in a composite electrode in lithium organic batteries. The polymer reveals a cell potential of 2.3 V and a promising capacity of 137 mAh/g. During the first 100 cycles, the capacity drops to 85% of the initial value. The influence of the charging speed on the charging/discharging properties of the batteries was further investigated.
Tetracyanoanthraquinodimethane polymers and use thereof
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Page/Page column 42; 43, (2018/03/07)
Novel tetracyanoanthraquinodimethane polymers and use thereof. The problem addressed was that of providing novel polymers which are preparable with a low level of complexity, with the possibility of controlled influence on the physicochemical properties thereof within wide limits in the course of synthesis, and which are usable as active media in electrical charge storage elements for high storage capacity, long lifetime and stable charging/discharging plateaus. Tetracyanoanthraquinodimethane polymers consisting of an oligomeric or polymeric compound of the general formula I have been found.
NOVEL 9,10-BIS(1,3-DITHIOL-2-YLIDENE)-9,10-DIHYDROANTHRACENE POLYMERS AND USE THEREOF
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, (2017/07/14)
The problem addressed was that of providing novel polymers which are preparable with a low level of complexity, with the possibility of controlled influence on the physicochemical properties thereof within wide limits in the course of synthesis, and which are usable as active media in electrical charge storage elements for high storage capacity, long lifetime and stable charging/discharging plateaus. 9,10-Bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene polymers consisting of an oligomeric or polymeric compound of the general formula I have been found.