134-01-0

Basic information

• Product Name: PEONIDIN CHLORIDE
• Synonyms: PEONIDIN CHLORIDE;3,4',5,7-TETRAHYDROXY-3'-METHOXYFLAVYLIUM CHLORIDE;3,5,7,4'-TETRAHYDROXY-3'-METHOXYFLAVYLIUM CHLORIDE;peonidin;3,5,7-trihydroxy-2-(4-hydroxy-3-methoxyphenyl)-1-benzopyrylium chloride;2-(4-hydroxy-3-methoxy-phenyl)chromene-3,5,7-triol;PEONIDIN CHLORIDE SNAP-N-SHOOT 0.1mg/mL(P);PEONIDIN CHLORIDE(P)
• CAS NO: 134-01-0
• Molecular Formula: C₁₆H₁₃O₆*Cl
• Molecular Weight: 336.72
• EINECS: 205-125-6
• Product Categories: Anthocyanins;Flavonoids
• Mol File: 134-01-0.mol
• Article Data: 1

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• Storage Temp.: −20°C
• CAS DataBase Reference: PEONIDIN CHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: PEONIDIN CHLORIDE(134-01-0)
• EPA Substance Registry System: PEONIDIN CHLORIDE(134-01-0)

Safety Data

• WGK Germany: 3
• F: 10-21
• Hazardous Substances Data: 134-01-0(Hazardous Substances Data)

Usage

Uses

Peonidin Chloride is a chemical dye for hair.

Synthetic route

5-benzoyl-peonidin chloride → peonidin chloride (134-01-0)

Conditions	Yield
With sodium hydroxide Erwaermen des Reaktionsprodukts mit Salzsaeure auf 60grad;

anthocyanin + hydrochloric acid → peonidin chloride (134-01-0)

peonin chloride → peonidin chloride (134-01-0)

Conditions	Yield
With hydrogenchloride

peonidin 3-O-[2-O-(2-O-(trans-sinapoyl)-glucosyl)-6-O-(trans-p-coumaroyl)-glucoside]-5-O-[6-O-(malonyl)-glucoside] → D-Glucose (2280-44-6) + malonic acid (141-82-2) + p-Coumaric Acid (7400-08-0) + trans-3,5-dimethoxy-4-hydroxycinnamic acid (530-59-6) + peonidin chloride (134-01-0)

Conditions	Yield
With hydrogenchloride; water at 100℃; for 1h;

peonidin 3-O-[2-O-(2-O-(trans-feruloyl)-glucosyl)-6-O-(trans-p-coumaroyl)-glucoside]-5-O-[6-O-(malonyl)-glucoside] → D-Glucose (2280-44-6) + (E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid (1135-24-6) + malonic acid (141-82-2) + p-Coumaric Acid (7400-08-0) + peonidin chloride (134-01-0)

Conditions	Yield
With hydrogenchloride; water at 100℃; for 1h;

peonidin 3-O-[2-O-(2-O-(trans-feruloyl)-glucosyl)-6-O-(cis-p-coumaroyl)-glucoside]-5-O-[6-O-(malonyl)-glucoside] → D-Glucose (2280-44-6) + (E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid (1135-24-6) + malonic acid (141-82-2) + (Z)-p-coumaric acid (501-98-4, 4501-31-9, 7400-08-0) + peonidin chloride (134-01-0)

Conditions	Yield
With hydrogenchloride; water at 100℃; for 1h;

peonidin chloride (134-01-0) + furan-2,3,5(4H)-trione pyridine (1:1) → 3,5-dihydroxyphenol (108-73-6) + 3-methoxy-4-hydroxybenzoic acid (121-34-6)

Conditions	Yield
Kochen mit Barytwasser;

peonidin chloride (134-01-0) + hydrogen peroxide → 3-methoxy-4-hydroxybenzoic acid (121-34-6)

UDP-glucose (133-89-1) + peonidin chloride (134-01-0) → peonidin 3-O-glucoside chloride

Conditions	Yield
With Glycine max (L.) Merr. cv. Clark His6-UDP-glucose:flavonoid 3-O-glucosyltransferase at 30℃; for 0.05h; pH=8; aq. buffer; regiospecific reaction;

Downstream Products

• 108-73-6 3,5-dihydroxyphenol 
• 121-34-6 3-methoxy-4-hydroxybenzoic acid 

Relevant articles and documents

Triacylated peonidin 3-sophoroside-5-glucosides from the purple flowers of Moricandia ramburii Webb.

Triacylated peonidin 3-sophoroside-5-glucosides were isolated from the purple flowers of Moricandia ramburii Webb. (Family: Brassicaceae), and determined to be peonidin 3-O-[2-O-(2-O-(trans-feruloyl)-glucosyl)-6-O-(trans-p- coumaroyl)-glucoside]-5-O-[6-O-(malonyl)-glucoside] (1), peonidin 3-O-[2-O-(2-O-(trans-feruloyl)-glucosyl)-6-O-(cis-p-coumaroyl)-glucoside] -5-O-[6-O-(malonyl)-glucoside] (2) and peonidin 3-O-[2-O-(2-O-(trans-sinapoyl)- glucosyl)-6-O-(trans-p-coumaroyl)-glucoside]-5-O-[6-O-(malonyl)-glucoside] (3), respectively, by chemical and spectroscopic methods. In addition, one known acylated cyanidin glycoside, cyanidin 3-O-[2-O-(2-O-(trans-feruloyl)-glucosyl)- 6-O-(trans-p-coumaroyl)-glucoside]-5-O-[6-O-(malonyl)-glucoside] (4), was also identified in the flowers. Peonidin glycosides have not been reported hitherto in floral tissues in to Brassicaceae.