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Usage

Uses

Used in Organic Synthesis:
(6Z)-6-[(2,2-dimethylhydrazino)methylidene]cyclohexa-2,4-dien-1-one is used as a key intermediate for the synthesis of various organic compounds. Its unique structure allows it to participate in a range of chemical reactions, making it a valuable component in the development of new molecules and materials.
Used in Chemical Research:
(6Z)-6-[(2,2-dimethylhydrazino)methylidene]cyclohexa-2,4-dien-1-one is also used in chemical research to study its properties, reactivity, and potential applications. Understanding its behavior in different reaction conditions can lead to the discovery of new synthetic pathways and the development of novel compounds with specific functions.
Used in Pharmaceutical Industry:
Although not explicitly mentioned in the provided materials, compounds with hydrazino groups are often found in the pharmaceutical industry as they can be used to develop new drugs or improve the properties of existing ones. (6Z)-6-[(2,2-dimethylhydrazino)methylidene]cyclohexa-2,4-dien-1-one may have potential applications in this field, but further research is required to explore its possibilities.
Used in Material Science:
(6Z)-6-[(2,2-dimethylhydrazino)methylidene]cyclohexa-2,4-dien-1-one's unique structure and reactivity may also make it suitable for use in material science, where it could be employed to create new materials with specific properties or to modify existing materials for improved performance.
It is important to handle (6Z)-6-[(2,2-dimethylhydrazino)methylidene]cyclohexa-2,4-dien-1-one with caution due to its potential chemical properties and reactivity. Further research is needed to fully understand its uses and potential hazards, ensuring safe and effective application in various industries.

Upstream product

• 90-02-8 salicylaldehyde 
• 57-14-7 N,N-Dimethylhydrazine 

Downstream Products

• 611-20-1 salicylonitrile 

Relevant academic research and scientific papers

Dynamic neighbouring participation of nitrogen lone pairs on the chromogenic behaviour of trans-bis(salicylaldiminato)Pt(ii) coordination platforms

The participation of neighbouring nitrogen lone pairs in the chromogenic control of trans-bis(salicylaldiminato)Pt(ii) platforms was examined, using newly designed Pt analogues bearing salicylaldehyde hydrazone ligands. A series of non-vaulted and vaulted Pt complexes (1-5) with salicylaldehyde hydrazones as trans-coordinated bidentate ligands were synthesized and characterized with regard to the chromogenic behaviour of the trans-bis(salicylaldiminato)Pt(ii) coordination platforms. X-ray diffraction and 2D NMR data demonstrated that, in the case of the non-vaulted N-monomethyl complexes 1, there was significant participation of neighbouring N(2) lone pairs in the d-π conjugation of the trans-bis(salicylaldiminato)Pt(ii) platforms owing to conformational fixation arising from intramolecular hydrogen bonding. In contrast, the lone pairs of the N,N-dimethyl analogues 2 made a much less significant contribution to the extension of the d-π conjugation, due to their high conformational mobility. Complexes 1-5 were found to have structure-dependent chromogenic properties in the solution state, such that the absorption spectra of the N-methyl, short-vaulted complexes 1 and 3 exhibited significant hypsochromic shifts relative to the N,N-dimethyl, long-vaulted analogues 2 and 5, which had spectra very similar to that of the trans-bis(salicylaldiminato)Pt(ii) complex 6. The introduction of MeO groups at the 3- and 5 positions on the aromatic rings of 1 and 2 gave rise to significant hypsochromic and bathochromic shifts, respectively. In addition, νmax - ET(30) plots for various solvents revealed that complexes 1-5 exhibit negative solvatochromism, in which the data obtained in alcoholic solvents are hypsochromically separated from those in non-alcoholic solvents for 1 and 3, an effect that is not observed for 2 and 5. Complexes 1-5 also exhibit emission enhancement upon addition of excess CH3SO3H in dimethyl sulfoxide, and a significant effect of the linker on quantum yields (Φ77 K) was observed in the case of the vaulted complexes. Density functional theory calculations (B3LYP/6-31G*, LanL2DZ) determined that the structure dependence of the chromogenic behaviour of these non-vaulted and polymethylene-vaulted hydrazone complexes can be attributed to variations in the participation of neighbouring nitrogen lone pairs in the d-π conjugation on the trans-bis(salicylaldiminato)Pt(ii) coordination platforms.