1341125-81-2Relevant articles and documents
Limno-CP: A natural-product-inspired 5-aryl-3(2 H)-furanone as scaffold for a library of α-modified enones
Amslinger, Sabine,Lindner, Simon K.
, p. 2671 - 2683 (2011)
A library of 5-aryl-3(2H)-furanones that are modified in the α-position of the α,β-unsaturated carbonyl system was prepared via simple one- to three-step transformations from one common scaffold. The 13C NMR characterization of the enone system showed a strong influence of the α-substituents, especially on the shifts of the α- and β-carbon atoms. Probing the addition chemistry of nucleophiles versus our α-modified enones, a 1,2-addition-elimination- was found, but no 1,4-addition. Georg Thieme Verlag Stuttgart. New York.