1341217-59-1Relevant articles and documents
Regio- and stereoselective olefination of phenol carbamates through C-H bond functionalization
Li, Bin,Ma, Jianfeng,Liang, Yujie,Wang, Nuancheng,Xu, Shansheng,Song, Haibin,Wang, Baiquan
, p. 1950 - 1962 (2013)
Two pathways that can be used to access ortho-olefinated phenol carbamate, including a ruthenium(II)-catalyzed oxidative olefination of phenol carbamate with acrylates and a rhodium(III)-catalyzed alkyne hydroarylation of phenol carbamate with internal alkynes through direct C-H activation, are reported. Both reactions afford substituted alkenes in a highly regio- and stereoselective manner. A highly regio- and stereoselective olefination of phenol carbamates through RuII-catalyzed oxidative olefination and Rh III-catalyzed alkyne hydroarylation are reported.
Ruthenium-catalyzed oxidative C-H alkenylation of aryl carbamates
Li, Jie,Kornhaass, Christoph,Ackermann, Lutz
supporting information, p. 11343 - 11345,3 (2012/12/12)
A cationic ruthenium(ii) catalyst enabled highly efficient oxidative alkenylations of electron-rich arenes bearing removable, weakly coordinating carbamates, and allowed for cross-dehydrogenative C-H bond functionalization in an aerobic manner. This journ
