134151-66-9Relevant academic research and scientific papers
Perfluorocyclobutane-based polyester(arylene ether)s for applications in integrated optics
Wong, Sharon,Ma, Hong,Jen, Alex K.-Y.,Barto, Rick,Frank, Curtis W.
, p. 5578 - 5585 (2007/10/03)
Novel ester-containing aryl trifluorovinyl ether monomers and the resulting perfluorocyclobutane aromatic ether polymers have been synthesized and characterized to exhibit desirable properties for low optical loss waveguide applications. The monomers were
Reactive compounds containing perfluorocyclobutane rings
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, (2008/06/13)
Novel compounds have at least one perfluorocyclobutane ring and at least two functional groups suitable for forming condensation polymers. Preferably the compounds have a structures represented by Formula II: STR1 wherein R and R' independently represent optionally inertly substituted groups; X and X' represent any molecular structures which link R and R' with the perfluorocyclobutane ring; n and n' are the number of G and G' groups, respectively; and G and G' independently represent any reactive functional groups or any groups convertible into reactive functional groups. The compound are preferably prepared by a process of thermally dimerizing trifluorovinyl compound to form a compounds of Formula I wherein G represents G or G' in Formula II; X represents X or X' of Formual II; and n represents n or n' of Formula II, to form a compound having a perfluorocyclobutane group.
Perfluorovinyl compounds
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, (2008/06/13)
Compounds have a structure represented by Formula I: wherein R represents an unsubstituted or inertly substituted hydrocarbyl group; each X is independently selected from the group consisting of groups having at least one non-carbon atom between R and --CF=CF2 ; and m is an integer of from 1 to about 3. Polymers formed from such compounds are also prepared. The compounds are preferably prepared by a method by a process comprising the steps of: (a) forming a salt having anion corresponding to a compound of Formula II: wherein X, R and m are as defined for Formula I; (b) reacting the salt with a 1,2-dihalo-1,1,2, 2-tetrafluoroethane wherein the halo groups are iodine, bromine, chlorine or mixtures thereof, at least one halo group being bromine or iodine, to form a compound of Formula III: wherein X, R and m are as defined for Formula I and each Z is independently iodine or bromine; (c) eliminating the halogen atoms represented by Z to form the perfluorovinyl compound represented by Formula I.
