134276-72-5Relevant academic research and scientific papers
STEREOSELECTIVE SYNTHESIS OF CIS-α,β-EPOXYKETONES VIA DIVALENT TIN ENOLATE
Mukaiyama, Teruaki,Haga, Toru,Iwasawa, Nobuharu
, p. 1601 - 1604 (1982)
A convenient method for the stereoselective synthesis of cis-β-substituted-α,β-epoxyketone is established employing Sn(OTf)2 mediated cross aldol reaction between α-bromoketone and aldehyde followed by successive treatment of the adduct with KF-dicyclohex
Efficient diastereoselective synthesis of anti-α-bromo-β-hydroxyketones
Brown, Herbert C.,Zou, Mu-Fa,Ramachandran, P. Veeraraghavan
, p. 7875 - 7877 (2007/10/03)
Anti-α-bromo-β-hydroxyketones were synthesized in high diastereoselectivity via the enolboration of a representative series of bromomethylketones using dicyclohexylboron chloride, followed by aldolization with aldehydes.
SYNTHETIC CONTROL LEADING TO CHIRAL COMPOUNDS
Mukaiyama, Teruaki,Iwasawa, Nobuharu,Stevens, Rodney W.,Haga, Toru
, p. 1381 - 1390 (2007/10/02)
A highly diastereoselective cross aldol reaction is developed using divalent tin enolates formed from stannous trifluoromethanesulfonate and carbonyl compounds.The reaction is extended to a highly enantioselective cross aldol reaction employing chiral dia
