STEREOSELECTIVE SYNTHESIS OF CIS-α,β-EPOXYKETONES VIA DIVALENT TIN ENOLATE

DOI: 10.1246/cl.1982.1601

Source and publish data:

Chemistry Letters p. 1601 - 1604 (1982)

Update date:2022-08-04

Topics:

Authors:

Mukaiyama, Teruaki

Haga, Toru

Iwasawa, Nobuharu

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Article abstract of DOI:10.1246/cl.1982.1601

A convenient method for the stereoselective synthesis of cis-β-substituted-α,β-epoxyketone is established employing Sn(OTf)2 mediated cross aldol reaction between α-bromoketone and aldehyde followed by successive treatment of the adduct with KF-dicyclohex

Full text of DOI:10.1246/cl.1982.1601

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