134281-47-3Relevant academic research and scientific papers
Preparation and reactions of functionalized magnesium carbenoids
Avolio, Salvatore,Malan, Christophe,Marek, Ilan,Knochel, Paul
, p. 1820 - 1822 (1999)
New functionalized magnesium carbenoids bearing an ester function have been prepared via an iodine-magnesium exchange reaction. These new carbenoids react with various electrophiles (60-88% yield). A substituted magnesium carbenoid has been prepared by su
Electrooxidative C-S cleavages as a neutral deprotection for carbocxylic acids
Kimura,Matsubara,Yamamoto,Sawaki
, p. 867 - 876 (2007/10/02)
C-S Bond cleavages of S-t-butyl thioates (1) and 4-methoxyphenylthiomethyl esters (2) are achieved electrochemically in an indirect and direct manner, respectively, in aqueous acetonitrile, affording an efficient method for deprotection of carboxylic acids under neutral conditions.
