134287-56-2

Basic information

• Product Name: 2-<2'-(N,N-dimethylamino)ethoxy>-3-<(E)-4-hexenyl>-1,4-cyclohexadiene
• Synonyms: 2-<2'-(N,N-dimethylamino)ethoxy>-3-<(E)-4-hexenyl>-1,4-cyclohexadiene
• CAS NO: 134287-56-2
• Molecular Weight: 249.396
• Mol File: 134287-56-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-<2'-(N,N-dimethylamino)ethoxy>-3-<(E)-4-hexenyl>-1,4-cyclohexadiene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-<2'-(N,N-dimethylamino)ethoxy>-3-<(E)-4-hexenyl>-1,4-cyclohexadiene(134287-56-2)
• EPA Substance Registry System: 2-<2'-(N,N-dimethylamino)ethoxy>-3-<(E)-4-hexenyl>-1,4-cyclohexadiene(134287-56-2)

Safety Data

• Hazardous Substances Data: 134287-56-2(Hazardous Substances Data)

Upstream product

• 31502-25-7 (E)-6-bromohex-2-ene 
• 134287-55-1 [2-(Cyclohexa-1,4-dienyloxy)-ethyl]-dimethyl-amine 
• 60653-76-1 <(E)-4-Hexenyl>-methansulfonat 
• 928-93-8 4-hexyn-1-ol 
• 3003-84-7 Tetrahydrofurfuryl chloride 

Relevant articles and documents

Regiochemistry and Stereochemistry of Intramolecular Photocycloaddition of Carbon-Carbon Double Bonds to Cyclohexenones

The intramolecular photocycloaddition mechanism of alkenes tethered by a three-methylene chain to cyclohexenones has been studied.It was found that the reversion from a 1,4-diradical intermediate to starting material is slow relative to the rate of photoadduct formation.Only "straight" closure was observed in the systems studied.For compounds 1-3 and 5, the assumption that the first bond is formed between the β-carbon of the enone and C-4' leading to a 1,4-diradical is supported.For the formation of compounds 6-11, possible mechanisms are discussed.