134305-26-3Relevant academic research and scientific papers
Pd-catalyzed cyclization and carbene migratory insertion: New approach to 3-vinylindoles and 3-vinylbenzofurans
Liu, Zhenxing,Xia, Ying,Zhou, Shiyi,Wang, Long,Zhang, Yan,Wang, Jianbo
, p. 5032 - 5035 (2013)
A Pd-catalyzed stereoselective synthesis of 3-vinylindoles and 3-vinylbenzofurans has been developed. The reaction merges the alkyne-based Pd-catalyzed cyclization and Pd carbene migratory insertion in a single catalytic cycle, generating a C-C single bond and a C=C double bond in one operation.
SYNTHESIS AND PHOTOCHEMICAL BEHAVIOUR OF SUBSTITUTED ETHYLENES; PYRROLE AND INDOLE DERIVATIVES
Galiazzo, Guido,Gennari, Giorgio,Bortolus, Pietro
, p. 67 - 71 (2007/10/02)
The trans isomers of three (3-indolyl)arylethylenes have been synthesized by a Perkin-type reaction.The corresponding isomers were obtained by photoisomerization. 2-styrylpyrrole in both the trans and cis forms was synthesized by a Wittig reaction.The spectral characteristics and photochemical behaviour of the synthesized compounds are reported.
