13431-59-9Relevant academic research and scientific papers
Toluates: unexpectedly versatile reagents
Lam, Kevin,Markó, István E.
experimental part, p. 10930 - 10940 (2010/02/28)
The mechanism of the monoelectronic reduction of aromatic esters has been investigated. The unexpected synthetic utility of the toluate moiety in the deoxygenation of alcohols and the allylation of ketones is also reported. Finally, the use of aromatic esters as robust, though easily removable, protecting groups is depicted.
Chemoselective chemical and electrochemical deprotections of aromatic esters
Lam, Kevin,Marko, Istvan E.
scheme or table, p. 2752 - 2755 (2009/11/30)
Alcohols can be easily and chemoselectively deprotected from the corresponding aromatic esters by using either SmI2/HMPA or by electrolysis In the presence of a proton source.
Indium triflate: An efficient catalyst for acylation reactions
Chauhan, Kamlesh K.,Frost, Christopher G.,Love, Ian,Waite, David
, p. 1743 - 1744 (2007/10/03)
Indium triflate is shown to be an extremely efficient catalyst for the acylation of alcohols and amines.
