134420-05-6

Basic information

• Product Name: (1R,3S,4S,7S)-1,3,4,5,6,7-Hexamethyl-3-p-tolyl-bicyclo[2.2.1]hept-5-en-2-one
• Synonyms: (1R,3S,4S,7S)-1,3,4,5,6,7-Hexamethyl-3-p-tolyl-bicyclo[2.2.1]hept-5-en-2-one
• CAS NO: 134420-05-6
• Molecular Weight: 282.426
• Mol File: 134420-05-6.mol

Chemical Properties

• CAS DataBase Reference: (1R,3S,4S,7S)-1,3,4,5,6,7-Hexamethyl-3-p-tolyl-bicyclo[2.2.1]hept-5-en-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,3S,4S,7S)-1,3,4,5,6,7-Hexamethyl-3-p-tolyl-bicyclo[2.2.1]hept-5-en-2-one(134420-05-6)
• EPA Substance Registry System: (1R,3S,4S,7S)-1,3,4,5,6,7-Hexamethyl-3-p-tolyl-bicyclo[2.2.1]hept-5-en-2-one(134420-05-6)

Safety Data

• Hazardous Substances Data: 134420-05-6(Hazardous Substances Data)

Upstream product

• 51631-67-5 α-methyl 4-methylphenylacetyl chloride 
• 4045-44-7 1,2,3,4,5-pentamethylcyclopentadiene 
• 134419-97-9 (4-methylphenyl)methylketene 

Relevant articles and documents

Ketene-diene [4 + 2] cycloaddition products via cation radical initiated diels-alder reaction or vinylcyclobutanone rearrangement

Whereas the thermal reaction of the aryl methyl ketenes 1a and 1b with 2 resulted, as anticipated, in the periselective formation of the vinylcyclobutanones 3-6, the aminium ion salt initiated cycloaddition afforded selectively the Diels-Alder products 10