134457-00-4Relevant academic research and scientific papers
Glassy dynamics of hydrogen-bonded heteroditopic molecules
Lou, Nan,Wang, Yangyang,Li, Haixia,Sokolov, Alexei P.,Xiong, Huiming
, p. 4455 - 4460 (2012)
A self-complementary heteroditopic molecule composed of thymine and diamidopyridine end groups and a flexible aliphatic interconnecting chain has been synthesized. The glassy dynamics of this hydrogen-bonded supramolecule have been investigated by using dielectric and rheological measurements, in combination with infra-red spectroscopy and solid-state 13C NMR experiments. Decoupling of main dielectric relaxation from viscosity has been found in the vicinity of the glass transition and the temperature dependence of viscosity appears to be stronger than that of dielectric relaxation. The unusual dynamic decoupling phenomenon is ascribed to the chemical/dynamic heterogeneity and formation of hydrogen bonds in the supramolecules.
