1346043-18-2Relevant articles and documents
Carbonyl-inserted organo-hybrids of a Dawson-type phosphovanadotungstate: Scope and chemoselective oxidation catalysis
Oble, Julie,Riflade, Benoit,Noel, Amandine,Malacria, Max,Thorimbert, Serge,Hasenknopf, Bernold,Lacote, Emmanuel
, p. 5990 - 5993 (2012/01/03)
The Dawson-type polyoxometalate (POM) [P2V3W 15O62]9- is a prototype for inclusion of carbonyls of amides, ureas, carbamates, and thiocarbamates into polyoxometallic structures. The carbonyl-inserted POMs catalyze the oxidation of sulfides. Chemoselectivity depends primarily on the proton content of the POM, but it is also influenced by the organic substituent.