13461-16-0

Basic information

• Product Name: NNDIMETHYLETHYLENETHIOUREA
• Synonyms: NNDIMETHYLETHYLENETHIOUREA;1,3-dimethyl-2-imidazolidinethion;1,3-dimethyl-2-Imidazolidinethione;2-Imidazolidinethione,1,3-dimethyl-;1,3-Dimethylimidazolidine-2-thione
• CAS NO: 13461-16-0
• Molecular Formula: C₅H₁₀N₂S
• Molecular Weight: 130.21
• Mol File: 13461-16-0.mol

Chemical Properties

• Melting Point: 110-112 °C(Solv: water (7732-18-5))
• Boiling Point: 282.6 °C at 760 mmHg
• Flash Point: 124.7 °C
• Appearance: /
• Density: 1.17 g/cm³
• Vapor Pressure: 0.00333mmHg at 25°C
• Refractive Index: 1.6
• PKA: 1.50±0.20(Predicted)
• CAS DataBase Reference: NNDIMETHYLETHYLENETHIOUREA(CAS DataBase Reference)
• NIST Chemistry Reference: NNDIMETHYLETHYLENETHIOUREA(13461-16-0)
• EPA Substance Registry System: NNDIMETHYLETHYLENETHIOUREA(13461-16-0)

Safety Data

• Hazardous Substances Data: 13461-16-0(Hazardous Substances Data)

Usage

Uses

Used in Rubber Industry:
NNDIMETHYLETHYLENETHIOUREA is used as a rubber vulcanization accelerator and antioxidant for improving the durability and heat resistance of natural and synthetic rubbers.
Used in Agrochemical Production:
NNDIMETHYLETHYLENETHIOUREA is used as an ingredient in the production of herbicides, fungicides, and pesticides, contributing to the effectiveness of these products in controlling plant diseases and pests.
Used in Metalworking Fluids:
NNDIMETHYLETHYLENETHIOUREA is used in the formulation of metalworking fluids to enhance their performance and protect metal surfaces during manufacturing processes.
Used in Pharmaceutical Applications:
NNDIMETHYLETHYLENETHIOUREA is used as a potential therapeutic agent for treating conditions related to nitric oxide imbalance, such as cardiovascular and neurological diseases, due to its strong inhibitory effect on nitric oxide synthase.
It is crucial to handle NNDIMETHYLETHYLENETHIOUREA with care due to its toxic and hazardous nature, ensuring safety in its applications across various industries.

InChI:InChI=1/C5H10N2S/c1-6-3-4-7(2)5(6)8/h3-4H2,1-2H3

Upstream product

• 80-73-9 1,3-dimethyl-2-imidazolidinone 
• 58708-60-4 N,N'-Dimethyl-2-aminoethan-dithiocarbaminsaeure 
• 917-54-4 methyllithium 
• 110-70-3 N,N`-dimethylethylenediamine 
• 67-68-5 dimethyl sulfoxide 
• 6160-65-2 1,1'-Thiocarbonyldiimidazole 
• 14103-77-6 1,3-dimethylimidazolidine 
• 23309-78-6 N-(2-hydroxyethyl)-N,N'-dimethylthiourea 
• 1911-01-9 1,1',3,3'-tetramethyl-2,2'-biimidazolidinylidene 
• 75-15-0 carbon disulfide 
• 61191-41-1 methyl iodide salt of N,N'-dimethylimidazolidine-2-thione 
• 58708-58-0 disodium N,N'-dimethylethylenebisdithiocarbamate 
• 138767-61-0 N,N'-dimethyl<(8-dimethylaminomethyl)naphthyl>phenylsila-2-imidazoline 
• 138767-62-1 [2-(1,3-Dimethyl-2-phenyl-[1,3,2]diazasilolidin-2-yl)-benzyl]-dimethyl-amine 

Downstream Products

• 80-73-9 1,3-dimethyl-2-imidazolidinone 
• 100-53-8 phenylmethanethiol 
• 131538-00-6 4-mercaptomethyl-1,8-dimercapto-3,6-dithiaoctane 
• 78872-76-1 phenylmethane dithiol 
• 1911-01-9 1,1',3,3'-tetramethyl-2,2'-biimidazolidinylidene 
• 286-28-2 cyclohexene sulfide 
• 33877-15-5 (R)-(+)-styrene sulfide 

Relevant articles and documents

Metal-Free C?H Borylation of N-Heteroarenes by Boron Trifluoride

Organoboron compounds are essential reagents in modern C?C coupling reactions. Their synthesis via catalytic C?H borylation by main group elements is emerging as a powerful tool alternative to transition metal based catalysis. Herein, a straightforward metal-free synthesis of aryldifluoroboranes from BF3 and heteroarenes is reported. The reaction is assisted by sterically hindered amines and catalytic amounts of thioureas. According to computational studies the reaction proceeds via frustrated Lewis pair (FLP) mechanism. The obtained aryldifluoroboranes are further stabilized against destructive protodeborylation by converting them to the corresponding air stable tetramethylammonium organotrifluoroborates.

THIOL COMPOUND PRODUCTION METHOD AND NOVEL THIATING AGENT

PROBLEM TO BE SOLVED: To provide: a thiol compound production method which allows selective production of a thiol compound of interest, inhibits production of by-products ending up wastes, is excellent in production efficiency, and can reduce production costs; and a novel thiating agent used for the method. SOLUTION: The thiol compound production method comprises: a step 1 of preparing a thiuronium salt by reacting at least one compound represented by the general formula (1) defined by R-(X)m with a thiating agent comprising at least one compound selected from compounds represented by the general formula (2) in the figure; and a step 2 of hydrolyzing the thiuronium salt to prepare a compound represented by the general formula (3) defined by R-(SH)m. SELECTED DRAWING: None COPYRIGHT: (C)2020,JPOandINPIT

Precursor reaction kinetics control compositional grading and size of CdSe1-: XSx nanocrystal heterostructures

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