134821-08-2

Upstream product

• 91608-15-0 tris(2,4,6-trimethoxyphenyl)phosphine 
• 12092-47-6 di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 
• 14104-20-2 silver tetrafluoroborate 
• 1277-43-6 cobaltocene 
• 134788-86-6 {Rh(P(C₆H₂(OCH₃)3)3)2(CO)2}⁽¹⁺⁾*BF₄^(1-)={Rh(P(C₆H₂(OCH₃)3)3)2(CO)2}(BF₄) 

Downstream Products

• 134788-86-6 {Rh(P(C₆H₂(OCH₃)3)3)2(CO)2}⁽¹⁺⁾*BF₄^(1-)={Rh(P(C₆H₂(OCH₃)3)3)2(CO)2}(BF₄) 
• 134788-87-7 {Rh(tris(2,4,6-trimethoxyphenyl)phosphine)2(CO)2}{BF₄}*CH₂Cl₂ 

Relevant academic research and scientific papers

Elucidation of the Reversible Carbon Monoxide Reactions of a Paramagnetic Rhodium(II) Complex

Coordination of carbon monoxide to the rhodium(II) ether-phosphine complex 2 1 initiates a redox reaction to produce the rhodium(III) complex 3 2 and the dicarbonyl rhodium(I) species 3; the latter readily loses a CO ligand to form 4 which enters into a second redox reaction with 4 to regenerate the original rhodium(II) radical 1.

Reversible carbon monoxide reactions of cationic Rh(I) and Rh(II) complexes

The syntheses, spectral properties, redox chemistry, and structures of complexes obtained from the reaction of carbon monoxide with a rare mononuclear Rh(II) species are described. The ionic compound [Rh(η3-TMPP)2][BF4]su