13491-70-8Relevant articles and documents
Voltammetric Studies on Some Arylhydrazones of α-Cyano Ketones and α-Cyano Esters
Abou-Elenien, G. M.,Ismail, N. A.,Hafez, T. S.
, p. 651 - 654 (2007/10/02)
The redox characteristics of the title compounds are extensively studied using DC-, cyclic voltammetry, coulometry, and controlled potential electrolysis in benzonitrile at platinum electrodes.These compounds are oxidized in one-electron transfer process followed by deprotonation which leads to dimerization.The reduction process differs according to the nature of the compound and the electron-withdrawing power of the substituent in the α-position.They can be reduced in a single two electron or two one electron waves leading in both cases to saturation of the hydrazonic moiety.