134953-19-8

Upstream product

• 67545-37-3 4-hydroxy-4-phenyl-hexanoic acid 
• 141-82-2 malonic acid 
• 2439-43-2 (2RS)-2-phenylbutanal 
• 25333-24-8 3-benzoylpropionic acid methyl ester 
• 2035-94-1 2-phenylbutan-1-ol 
• 925-90-6 ethylmagnesium bromide 

Downstream Products

• 74072-53-0 methyl 4-(4-acetylphenyl)hexanoate 
• 6002-99-9 methyl 4-phenylhexanoate 
• 135815-65-5 methyl 4-phenylhex-3-enoate 
• 5354-04-1 4-phenylhexanoic acid 

Relevant academic research and scientific papers

An approach to enantioselective 5-endo halo-lactonization reactions

Enantioselective lactonization of 4-substituted but-3-enoic acids using iodobis(N-methylephedrine) hexafluoroantimonate in dichloromethane at low temperatures is reported. The presence of bis(N-methylephedrine)silver(I) hexafluoroantimonate, derived from

A New Approach to Aromatic Substitution - para-Specific Alkylation of Acetophenone by Alkyl Radicals in Strongly Acidic Media

Acetophenone in 25percent oleum is substituted by various alkyl radicals specifically in the para-position.The radicals used include cyclohexyl, 3-chloro-1-methylpropyl, 3-bromo-1-methylpropyl, 4-chloro-1-methylbutyl, 4-bromo-1-methylbutyl, 5-bromo-1-methylpentyl, 5-acetoxy-1-methylpentyl, 3-carboxy-1-methylpropyl, 4-carboxy-1-methylbutyl and 5-carboxy-1-methylpentyl.They were all generated by hydrogen atom abstraction at the radical position by dimethylaminium radicals, generated in turn from protonated dimethylchloramine and ferrous sulphate.Yields were generally poor to moderate but utilised simple conditions and cheap reagents.