134986-41-7Relevant academic research and scientific papers
Green alkoxyiodination of cyclohexene mediated by natural clay
Villegas, Raul A. S.,Do Espirito Santo Jr., Jose Luiz,Sanseverino, Antonio M.,De Mattos, Marcio C. S.,De Aguiar, Monica R. M. P.,Guarino, Alcides W. S.
, p. 1627 - 1631 (2005)
The reaction of cyclohexene with iodine and alcohols (ethanol, isopropanol, and t-butanol) at room temperature is effectively mediated by clays to produce the corresponding trans-β-alkoxy-iodocyclohexane. Copyright Taylor & Francis, Inc.
Dichloroiodoisocyanuric acid: A new reagent for regioselective coiodination of alkenes and iodination of activated arenes
Da Silva Ribeiro, Rodrigo,Esteves, Pierre M.,De Mattos, Marcio C.S.
experimental part, p. 228 - 235 (2012/05/05)
Dichloroiodoisocyanuric acid was prepared in 93% by heating trichloroisocyanuric acid with 1.05 mol equiv. of iodine. This new reagent is very efficient for regioselective electrophilic iodination of activated arenes. Alkenes react with dichloroiodoisocyanuric acid in the presence of oxygenated nucleophiles (water, alcohols, and acetic acid), leading to the corresponding iodohydrins, β-iodoethers and β-iodoacetates with reaction times of less than one minute and with a high degree of regioselectivity. Enol ethers resulted in the regioselective formation of the corresponding iodine-dialkylacetals. Experimental results and DFT calculations showed that dichoroiodoisocyanuric acid is more reactive with unsaturated systems than triiodoisocyanuric acid.
Triiodoisocyanuric acid: a new and convenient reagent for regioselective coiodination of alkenes and enolethers with oxygenated nucleophiles
Ribeiro, Rodrigo da S.,Esteves, Pierre M.,de Mattos, Marcio C.S.
, p. 8747 - 8751 (2008/03/18)
The reaction of triiodoisocyanuric acid (prepared from I2 and trichloroisocyanuric acid in 90% yield) with alkenes in the presence of oxygenated nucleophilic solvents (alcohols, AcOH and H2O) led to the corresponding β-iodoethers, β-iodoacetates and iodohydrins, in 66-98% isolated yield. Enolethers reacted with triiodoisocyanuric acid in MeOH to produce dialkylacetals (70-83%).
A New Alkoxyiodination and Nitratoiodination of Olefins Using Iodine-Cerium(IV) Ammonium Nitrate
Horiuchi, C. Akira,Nishio, Yoshihiko,Gong, Dan,Fujisaki, Takanori,Kiji, Shinji
, p. 607 - 610 (2007/10/02)
Reactions of cycloolefins with iodine-cerium(IV) ammonium nitrate in alcohols (methanol, ethanol, 1-propanol, and 2-propanol) under reflux gave the corresponding vicinal alkoxyiodocycloalkanes in good yields.In the case of t-butyl alcohol, trans-iodo nitr
