135019-28-2

Upstream product

• 100-42-5 styrene 
• 135019-26-0 9,15-bis(trifluoromethylsulfonyloxy)<2^12,13><5.2>metacyclophane 
• 4877-10-5 1,5-bis(4-methoxyphenyl)pentane 
• 135019-25-9 9,15-dihydroxy<2^12,13><5.2>metacyclophane 
• 135019-24-8 9,15-dimethoxy<2^12,13><5.2>metacyclophane 
• 136577-67-8 1,5-bis<3-(1-hydroxyethyl)-4-methoxyphenyl>pentane 
• 136559-20-1 1,5-bis(3-acetyl-4-methoxyphenyl)pentane 

Downstream Products

• 135019-30-6 C₃₇H₃₆ 

Relevant academic research and scientific papers

Stereoselective Synthesis of Meta- and Three-bridged Cyclophanes with Intramolecular Photocycloaddition by Using the Steric Effect of Methoxyl Group

Key Words: Cyclophane; stereoselectivity; conformation; regioisomer; photocycloaddition; torsional angle.Dimethoxymetacyclophanes 9 (n=2,3,4,5, and 6) and 10 were stereoselectively obtained in 61-87percent yields by means of photocycloaddition.

Synthesis of three-bridged cyclophanes via meta- and ortho-cyclophane

Three-bridged cyclophanes 6a-b and 10 were obtained from directly olefinated meta- and ortho-cyclophanes under [2 + 2] photocycloaddition.