1350754-55-0Relevant academic research and scientific papers
Rhodium(iii)-catalyzed oxidative carbonylation of benzamides with carbon monoxide
Du, Ya,Hyster, Todd K.,Rovis, Tomislav
, p. 12074 - 12076 (2011)
An efficient strategy for the oxidative carbonylation of aromatic amides via C-H/N-H activation to form phthalimides using an Rh(iii) catalyst has been developed. The reaction shows a preference for C-H bonds of electron-rich aromatic amides and tolerates a variety of functional groups. The Royal Society of Chemistry 2011.
Ruthenium(II)-Catalyzed Redox-Neutral C-H Alkylation of Arylamides with Unactivated Olefins
Shambhavi, Chikkabagilu Nagaraju,Jeganmohan, Masilamani
, p. 4849 - 4854 (2021)
A Ru(II)-catalyzed weak chelating group-aided ortho-C-H alkylation of arylamides with unactivated olefins in a redox-neutral fashion has been demonstrated. The present alkylation reaction was well-suited for various substituted arylamides and unactivated aliphatic alkenes. In this alkylation reaction, pivalic acid plays dual role in which it delivers the proton source in a protonation step and the corresponding acetate moiety deprotonates the ortho-C-H bond of the arylamides.
