13509-71-2Relevant academic research and scientific papers
Study of boron-nitrogen dative bonds using azetidine inversion dynamics
Hoang, Cam Thuy,Prokes, Ivan,Clarkson, Guy J.,Rowland, Matthew J.,Tucker, James H. R.,Shipman, Michael,Walsh, Tiffany R.
, p. 2509 - 2511 (2013/04/10)
A method for probing the strength of B-N dative bonds is reported. The activation parameters for nitrogen inversion in a series of azetidines tethered to boronate esters have been quantified by VT-NMR and the measured barriers correlated with data obtained by 11B NMR, X-ray crystallography and MP2 calculations.
SYNTHESIS OF AZETIDINES FROM β-CHLORO IMINES
Sulmon, Paul,Kimpe, Norbert De,Schamp, Niceas,Tinant, Bernard,Declercq, Jean-Paul
, p. 3653 - 3670 (2007/10/02)
The reaction of β-chloro imines 4 with potassium cyanide in methanol or with lithium aluminium hydride in dry ether gave rise to 2-cyanoazetidines 5 and azetidines 21.The reaction proceeded by nucleophilic addition of cyanide or hydride across the carbon-
Formation of azetidines by decarboxylation of tetrahydro-1,3-oxazin-2-ones
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, (2008/06/13)
Azetidines are prepared by decarboxylating a tetrahydro-1,3-oxazin-2-one.
