106367-20-8Relevant academic research and scientific papers
Synthesis of 1-amino-2,2-dialkylcyclopropanecarboxylic acids from β-chloroaldimines
De Kimpe,Sulmon,Stevens
, p. 4723 - 4738 (2007/10/02)
A variety of hydrogen cyanide adducts of β-chloroaldimines using acetone cyanohydrin were prepared. The reactive behaviour of these α-amino-γ-chloronitriles towards bases was investigated with the aim to generate 1-aminocyclopropanecarbonitriles, which ar
SYNTHESIS OF AZETIDINES FROM β-CHLORO IMINES
Sulmon, Paul,Kimpe, Norbert De,Schamp, Niceas,Tinant, Bernard,Declercq, Jean-Paul
, p. 3653 - 3670 (2007/10/02)
The reaction of β-chloro imines 4 with potassium cyanide in methanol or with lithium aluminium hydride in dry ether gave rise to 2-cyanoazetidines 5 and azetidines 21.The reaction proceeded by nucleophilic addition of cyanide or hydride across the carbon-
Synthesis of β-Chloroimines
Sulmon, Paul,Kimpe, Norbert De,Verhe, Roland,Buyck, Laurent De,Schamp, Niceas
, p. 192 - 195 (2007/10/02)
β-Chloroimines 6 have been prepared from β-chlorocarbonyl compounds 5 by reaction with primary amines via two major approaches.
