13511-13-2

Basic information

• Product Name: 1-ALLYLCYCLOHEXENE
• Synonyms: 1-ALLYLCYCLOHEXENE;Cyclohexene, 1-(2-propenyl)-
• CAS NO: 13511-13-2
• Molecular Formula: C₉H₁₄
• Molecular Weight: 122.21
• Mol File: 13511-13-2.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 162.66°C (rough estimate)
• Flash Point: 31.3°C
• Appearance: /
• Density: 0.8401 (estimate)
• Vapor Pressure: 4.05mmHg at 25°C
• Refractive Index: 1.4765
• CAS DataBase Reference: 1-ALLYLCYCLOHEXENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-ALLYLCYCLOHEXENE(13511-13-2)
• EPA Substance Registry System: 1-ALLYLCYCLOHEXENE(13511-13-2)

Safety Data

• Hazardous Substances Data: 13511-13-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H14/c1-2-6-9-7-4-3-5-8-9/h2,7H,1,3-6,8H2

Upstream product

• 1123-34-8 1-allyl-1-cyclohexanol 
• 92085-71-7 1-allyl-2,8,9-trioxa-5-aza-1-silabicyclo<3.3.3>undecane 
• 108-94-1 cyclohexanone 
• 762-72-1 allyl-trimethyl-silane 
• 106-95-6 allyl bromide 
• 822-87-7 2-Chlorocyclohexanone 
• 1122-84-5 1-ethoxycyclohexene 
• 920-66-1 1,1,1,3',3',3'-hexafluoro-propanol 
• 52890-21-8 3-(cyclohex-1'-enyl)propyl p-nitrobenzenesulfonate 
• 75-91-2 tert.-butylhydroperoxide 
• 286-28-2 cyclohexene sulfide 
• 1730-25-2 allylmagnesium bromide 
• 861547-53-7 1-chloro-1-allyl-cyclohexane 

Downstream Products

• 53097-99-7 C₁₅H₂₀ClOP 
• 53097-98-6 3-phenyl-octahydro-cyclopropa[c]phosphindole 3-oxide 
• 217079-80-6 C₁₉H₃₂BCl 
• 175656-35-6 (4aR,8aR)-1-((1R,2S,3R,5R)-2,6,6-Trimethyl-bicyclo[3.1.1]hept-3-yl)-decahydro-benzo[b]borinine 
• 1678-92-8 propylcyclohexane 
• 103-65-1 phenylpropane 
• 1589528-90-4 (E)-5-(cyclohex-1-en-1-yl)-2-methyl-2-nitro-1-phenylpent-4-en-1-one 
• 69238-90-0 dichloro-(3-cyclohex-1-enyl-propyl)-silane 
• 22516-18-3 3-(cyclohex-1-en-1-yl)propan-1-ol 

Relevant articles and documents

Applications of allylsamarium bromide as a grignard reagent and a singleelectron transfer reagent in the one-pot synthesis of dienes and trienes

The utility of allylsamarium bromide, both as a nucleophilic reagent and a single-electron transfer (SET) reagent in the reaction of α-halo, γ-halo-αβ-unsaturated ketones and esters with allylsamarium bromide is reported for the first time in this paper. From a synthetic point of view, a general, efficient and experimentally simple one-pot method for the preparation of 1,4-dienes and trienes is developed. A possible mechanism of the transformation is proposed.

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Reaction of alkyl hydroperoxides (1(ary), 2(ary) or 3(ary)) upon tertiary alkyl trichloroacetimidates under acidic catalysis yielded unsymmetrical dialkyl peroxides with yields in the range 30-70%.

Reactivity of hypervalent species of silicon: cleavage of the allyl-silicon bond

The reactivities of the silicon-allyl bonds in two kinds of pentacoordinated silicon species CH2=CHCH2Si(o-O2C6H4)2-NMe4+ (1) and CH2=CHCH2Si(OCH2CH2)3N (2) has been compared.In the allyl transfer to carbonyl compounds under nucleophilic conditions (NaOMe, KF or Bu4NF) and electrophilic conditions (TiCl4, AlCl3, BF3) these two species show quite different behaviour.Complex 1 is activated by nucleophiles, while for 2 transfer occurs under electrophilic conditions.These results indicate that the reactivity of these species is a function of their overall charge and geometry.