135139-68-3Relevant academic research and scientific papers
Syntheses and structures of overcrowded silanedichalcogenols and their applications to the syntheses of silanedichalcogenolato complexes
Tanabe, Taro,Mizuhata, Yoshiyuki,Takeda, Nobuhiro,Tokitoh, Norihiro
experimental part, p. 353 - 365 (2009/04/13)
Overcrowded silanedichalcogenols Tbt(Mes)Si(EH)(E′H), such as silanedithiol (E = E′ = S), hydroxysilanethiol (E = O, E′ = S) and hydroxysilaneselenol (E = O, E′ = Se), bearing an efficient combination of steric protection groups, Tbt and Mes (Tbt = 2,4,6-
First structural characterization of silanedithiol and its application toward the synthesis of silanedithiolato complexes
Tanabe, Taro,Takeda, Nobuhiro,Tokitoh, Norihiro
, p. 1225 - 1228 (2008/02/06)
In this paper, we report the synthesis and the structural characterization of stable examples of silanedithiol [Tbt(Mes)Si(SH)2 (1)], hydroxysilanethiol [Tbt(Mes)Si(OH)(SH) (3)], and hydroxysilaneselenol [Tbt(Mes)Si(OH)(SeH) (7)], which are kin
SYNTHESIS AND REACTIONS OF NOVEL ORGANOSULFUR COMPOUNDS HAVING A HIGHLY STERICALLY BULKY GROUP, 2,4,6-TRISPHENYL
Tokitoh, Norihiro,Takahashi, Masaki,Matsumoto, Tsuyoshi,Suzuki, Hiroyiki,Matsuhashi, Yasusuke,Okazaki, Renji
, p. 161 - 164 (2007/10/02)
Novel cyclic metallatetrasulfides containing Group 14 metals have been synthesized by the thermal reactions of the corresponding metal hydrides substituted by the title new steric protection group.The structure of newly obtained metallacyclopolysulfides is of great interest in comparison with that of the previously reported di-?-cyclopentadienylmetal pentasulfides of titanium(IV) and vanadium(IV).Attempts to prepare the metal-sulfur double bond compounds from the metallacyclopolysulfides are also described.
