13516-02-4

Basic information

• Product Name: Benzoic acid, 2-amino-, methyl ester, hydrochloride
• CAS NO: 13516-02-4
• Molecular Formula: C8H9NO2.ClH
• Molecular Weight: 187.626
• Mol File: 13516-02-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2-amino-, methyl ester, hydrochloride(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-amino-, methyl ester, hydrochloride(13516-02-4)
• EPA Substance Registry System: Benzoic acid, 2-amino-, methyl ester, hydrochloride(13516-02-4)

Safety Data

• Hazardous Substances Data: 13516-02-4(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 118-92-3 anthranilic acid 

Downstream Products

• 798573-58-7 2-[(2E,6E)-8-(tert-Butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienylamino]-benzoic acid methyl ester 
• 882769-19-9 C₁₇H₁₇NO₃ 
• 1234571-06-2 2-{2-[(3Z)-5-cyano-1-cyclohexyl-2,6-dioxo-4-propyl-1,6-dihydro-2H-pyridin-3-ylidene]hydrazin-1-yl}benzoic acid methyl ester 
• 1234571-14-2 5-cyano-1-(2-methoxycarbonylphenyl)-6-oxo-4-propyl-1,6-dihydropyridazine-3-carboxylic acid ethyl ester 
• 1234571-24-4 5-amino-7-ethyl-3-(2-methoxycarbonylphenyl)-4-oxo-3,4-dihydrothieno[3,4-d]pyridazine-1-carboxylic acid ethyl ester 
• 1234571-12-0 2-[2-(1-ethoxycarbonyl-2-oxopentylidene)hydrazino]benzoic acid methyl ester 
• 610-96-8 methyl chlorobenzoate 
• 1489277-71-5 (S)-methyl 2-(2-(2-(4-(benzyloxy)phenyl)-1-(cyclohexanecarboxamido)ethyl)thiazole-4-carboxamido)benzoate 
• 1375149-43-1 N,N'-(1,4-phenylene)bis(2-(2-(2-methoxycarbonylphenyl)hydrazono)-3-oxo-3-phenylpropanamide) 
• 142131-88-2 2-<(4-Pyridylacetyl)amino>-benzoesaeure-methylester-hydrochlorid 

Relevant articles and documents

Organosilicon synthesis of isocyanates: III. Synthesis of aliphatic, carbocyclic, aromatic, and alkylaromatic isocyanatocatboxylic acid esters

A series of aminoacid esters was prepared by treating the aminoacid suspensions in ethanol with thionyl chloride. Best conversion of aminoacid esters to corresponding isocyanates was achieved in the case of aromatic and carbocyclic aminoesters by phosgeneation of their N-silyl derivatives, and in the case of aliphatic and alkylaromatic aminoesters by phosgeneation of O-silyl or N,O-bissilylurethanes on their basis. In the last case additional step of esterification of the by-products isocyanatoalkylcarboxylic acid chlorides is required after phosgeneation. Unusual generation of cynnamates and intramolecular N→O-migration of trimethylsilyl group in the solutions of silylated alkylaromatic β-aminoacid esters were found. Pleiades Publishing, Inc., 2006.