1352033-69-2

Upstream product

• 80638-48-8 3-(3'-methoxy-4'-hydroxyphenyl)propionaldehyde 
• 69172-20-9 3-(3-methoxy-4-benzyloxyphenyl)propionaldehyde 
• 121-33-5 vanillin 
• 100-39-0 benzyl bromide 
• 2426-87-1 3-methoxy-4-(phenylmethoxy)benzaldehyde 
• 1352033-60-3 (5S)-7-[4-(benzyloxy)-3-methoxyphenyl]-5-[(4-methoxybenzyl)oxy]-1-hepten-3-one 
• 55708-65-1 1-(benzyloxy)-4-ethenyl-2-methoxybenzene 
• 1352033-66-9 (3S)-5-[4-(benzyloxy)-3-methoxyphenyl]-3-[(4-methoxybenzyl)oxy]pentan-1-ol 
• 1352033-65-8 (4S)-4-[4-(benzyloxy)-3-methoxyphenethyl]-2-(4-methoxyphenyl)-1,3-dioxane 
• 1352033-64-7 (3S)-5-[4-(benzyloxy)-3-methoxyphenyl]pentane-1,3-diol 
• 1352033-63-6 (2S,3S)-3-[4-(benzyloxy)-3-methoxyphenethyl]oxiran-2-ylmethanol 
• 1352033-68-1 C₂₉H₃₄O₅ 
• 1352033-67-0 C₂₇H₃₀O₅ 
• 1352033-62-5 (E)-5-[4-(benzyloxy)-3-methoxyphenyl]-2-penten-1-ol 

Downstream Products

• 1352033-70-5 (E,5S)-1,7-di[4-(benzyloxy)-3-methoxyphenyl]-5-hydroxy-1-hepten-3-one 
• 1352033-71-6 (1S,3R,4E)-1-[4-(benzyloxy)-3-methoxyphenethyl]-5-[4-(benzyloxy)-3-methoxyphenyl]-3-hydroxy-4-pentenyl acetate 
• 1352033-72-7 (1S,3R,4E)-3-(acetyloxy)-1-[4-(benzyloxy)-3-methoxyphenethyl]-5-[4-(benzyloxy)-3-methoxyphenyl]-4-pentenyl acetate 

Relevant academic research and scientific papers

Synthesis of diarylheptanoids, (5S)-5-acetoxy-1,7-bis(4-hydroxy-3- methoxyphenyl)-3-heptanone and (3S,5S)-3,5-diacetoxy-1,7-bis(4-hydroxy-3- methoxyphenyl)heptane

The total syntheses of the first examples of diarylheptanoid natural products (5S)-5-acetoxy-1,7-bis(4-hydroxy-3-methoxyphenyl)-3-heptanone 1, and (3S,5S)-3,5-diacetoxy-1,7-bis(4-hydroxy-3-methoxyphenyl)heptane 2 isolated from the rhizomes of Zingiber officinale were accomplished using Sharpless epoxidation and cross-metathesis reactions as the key steps.