1352319-05-1

Basic information

• Product Name: (1R,3R,4S,5R)-1,4-bis(benzyloxy)-3-((tert-butyldimethylsilyl)oxy)-6-oxabicyclo[3.2.1]octan-7-one
• Synonyms: (1R,3R,4S,5R)-1,4-bis(benzyloxy)-3-((tert-butyldimethylsilyl)oxy)-6-oxabicyclo[3.2.1]octan-7-one
• CAS NO: 1352319-05-1
• Molecular Weight: 468.665
• Mol File: 1352319-05-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,3R,4S,5R)-1,4-bis(benzyloxy)-3-((tert-butyldimethylsilyl)oxy)-6-oxabicyclo[3.2.1]octan-7-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,3R,4S,5R)-1,4-bis(benzyloxy)-3-((tert-butyldimethylsilyl)oxy)-6-oxabicyclo[3.2.1]octan-7-one(1352319-05-1)
• EPA Substance Registry System: (1R,3R,4S,5R)-1,4-bis(benzyloxy)-3-((tert-butyldimethylsilyl)oxy)-6-oxabicyclo[3.2.1]octan-7-one(1352319-05-1)

Safety Data

• Hazardous Substances Data: 1352319-05-1(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 163217-18-3 (1R,3R,4S,5R)-3-[(tert-butyldimethylsilyl)oxy]-1,4-dihydroxy-6-oxa-bicyclo[3.2.1]octan-7-one 
• 77-95-2 D-(-)-quinic acid 

Downstream Products

• 1352319-06-2 (1R,3R,4S,5R)-benzyl 1,4-bis(benzyloxy)-3-((tert-butyldimethylsilyl)oxy)-5-hydroxycyclohexanecarboxylate 
• 1352319-09-5 C₂₇H₃₈O₆Si 
• 1352319-07-3 (1S,3R,4S,5R)-benzyl 1,4-bis(benzyloxy)-3,5-dihydroxycyclohexanecarboxylate 
• 1352319-08-4 3,3'-(((1R,2S,3R,5S)-2,5-bis(benzyloxy)-5-((benzyloxy)carbonyl)cyclohexane-1,3-diyl)bis(oxy))bis(3-oxopropanoic acid) 
• 1352319-04-0 3,3'-(((1R,2S,3R,5S)-5-carboxy-2,5-dihydroxycyclohexane-1,3-diyl)bis(oxy))bis(3-oxopropanoic acid) 
• 2450-53-5 3,5-di-O-caffeoylquinic acid 

Relevant articles and documents

Total synthesis of 3,5-O-dicaffeoylquinic acid and its derivatives

We report the first total synthesis of 3,5-O-dicaffeoylquinic acid and its derivatives, 3,5-O-diferuloylquinic acid and 3,5-(3,4-dimethoxycinnamyl)quinic acid, in a nine-step sequence. The key step involves Knoevenagel condensations between vanillin, 3,4-dimethoxybenzaldehyde or 4-hydroxy-3-methoxybenzaldehyde and the dimalonate ester of quinic acid.