13524-72-6

Basic information

• Product Name: Phenol, 2-(1-cyclohexen-1-yl)-
• CAS NO: 13524-72-6
• Molecular Formula: C12H14O
• Molecular Weight: 174.243
• Mol File: 13524-72-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phenol, 2-(1-cyclohexen-1-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2-(1-cyclohexen-1-yl)-(13524-72-6)
• EPA Substance Registry System: Phenol, 2-(1-cyclohexen-1-yl)-(13524-72-6)

Safety Data

• Hazardous Substances Data: 13524-72-6(Hazardous Substances Data)

Upstream product

• 14003-77-1 3-(2-hydroxyphenyl)cyclohexene 
• 13524-79-3 1,2,3,4,4a,9b-hexahydrodibenzo[b,d]furan 
• 108-94-1 cyclohexanone 
• 95-56-7 2-hydroxybromobenzene 
• 4203-50-3 2-phenoxytetrahydropyran 
• 108-95-2 phenol 
• 59043-51-5 2-(1-Hydroxy-cyclohexyl)-phenol 
• 5614-35-7 3-phenoxycyclohexene 

Downstream Products

• 1026852-56-1 1-cyclohexenyl-2-(2-propynyloxy)benzene 

Relevant articles and documents

Cascade Claisen and Meinwald Rearrangement for One-Pot Divergent Synthesis of Benzofurans and 2 H-Chromenes

A new cascade approach has been developed for the one-pot four-step divergent synthesis of polysubstituted benzofurans and 2H-chromenes, featuring a novel cascade aromatic Claisen rearrangement/Meinwald rearrangement/dehydrative or oxidative cyclization. This new method was demonstrated with 39 examples tolerating different substitutions at an epoxide, allylic ether, and aromatic ring, and we showcased its utility with the first total synthesis of natural product liparacid A in seven steps.

REACTION OF PHENOL WITH CYCLOHEXANONE IN THE PRESENCE OF ALUMINUM PHENOLATE

The reaction of phenol with cyclohexanone in the presence of aluminum phenolate leads to a mixture of products of ether and phenolic character and also a mixture of the dimer and trimer of the initial ketone.As a rule 1-(2-hydroxyphenyl)cyclohexene predominates in the mixture.