135250-08-7Relevant academic research and scientific papers
Highly Stereoselective Synthesis of Tetrasubstituted Vinyl Selenides via Rhodium-Catalyzed [1,4]-Acyl Migration of Selenoesters and Diazo Compounds
Liu, Xun-Shen,Li, Mingjia,Dong, Kexin,Peng, Shaoting,Liu, Lu
supporting information, p. 2175 - 2180 (2022/04/07)
Herein, we disclose a highly stereoselective Rh(II)-catalyzed 1,4-Acyl rearrangement of selenium esters and α-diazo carbonyl compounds, which provides an efficient method for synthesizing tetrasubstituted vinyl selenides. Furthermore, this reaction also offers a synthetic tool for medium and large ring compounds.
Crystalline Sodium Selenocarboxylates - Synthesis and Characterization
Kato, Shinzi,Kageyama, Hideki,Takagi, Kazutaka,Mizoguchi, Kazuaki,Murai, Toshiaki
, p. 898 - 910 (2007/10/02)
A series of sodium selenocarboxylates 2 were isolated from the reaction of diacyl selenides with sodium ethanolate and characterized.A convenient preparation of the sodium salts 2 by the direct reaction of acyl chlorides with sodium selenide was also esta
