1352831-83-4

Basic information

• Product Name: (2S,4R,5R,6E)-2-benzoyloxy-5-diethylisopropylsilyloxy-4-methyloct-6-en-3-one
• Synonyms: (2S,4R,5R,6E)-2-benzoyloxy-5-diethylisopropylsilyloxy-4-methyloct-6-en-3-one
• CAS NO: 1352831-83-4
• Molecular Weight: 404.622
• Mol File: 1352831-83-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,4R,5R,6E)-2-benzoyloxy-5-diethylisopropylsilyloxy-4-methyloct-6-en-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,4R,5R,6E)-2-benzoyloxy-5-diethylisopropylsilyloxy-4-methyloct-6-en-3-one(1352831-83-4)
• EPA Substance Registry System: (2S,4R,5R,6E)-2-benzoyloxy-5-diethylisopropylsilyloxy-4-methyloct-6-en-3-one(1352831-83-4)

Safety Data

• Hazardous Substances Data: 1352831-83-4(Hazardous Substances Data)

Upstream product

• 125948-63-2 (S)-2-hydroxypentan-⁽³⁾-one 
• 107149-56-4 chlorodiethylisopropylsilane 
• 173726-06-2 (2S,4R,5R,6E)-2-benzoyloxy-5-hydroxy-4-methyloct-6-en-3-one 
• 93-97-0 benzoic acid anhydride 
• 160666-92-2 (S)-2-benzoyloxypentan-3-one 

Relevant articles and documents

Stereocontrolled total synthesis of (+)-concanamycin F: The strategic use of boron-mediated aldol reactions of chiral ketones

A highly stereocontrolled total synthesis of the 18-membered macrolide (+)-concanamycin F, a potent inhibitor of vacuolar ATPases, is described that proceeds in 5.8% yield over 26 steps. The three key fragments, C1-C13 vinyl iodide, C14-C22 vinyl stannane