135309-19-2Relevant academic research and scientific papers
Reaction of styrene with sulfur and triiron dodecacarbonyl and the molecular structure of the complex Fe2(CO)6(SCH2S)
Nekhaev,Kolobkov,Toshev,Dustov,Aleksandrov
, p. 827 - 830 (1991)
Reaction of excess styrene with Fe3(CO)12 and sulfur (60°C, 15 h, Ar, S/Fe3(CO)12 0.6 g-atom/mole) gave Fe2(CO)6S2, Fe3(CO)9S2, Fe2(CO)6(S2CO), Fe2(CO)6S2(PhCHCH2), PhCHCH2S4, and a novel binuclear complex Fe2(CO)6(S2CH2S), whose structure was analyzed by x-ray crystallography. The crystals are monoclinic, a=7.764(3), b=13.205(4), c=6.628(6) A, β=98.97(3)°. V=671.2(7) A3, Z=2, space group P21/m. The bond lengths are Fe-Fe 2.520(2), Fe-S 2.236(2), S-S 2.078(4), C-S 1.825(12), Fe-CO 1.784(8), and C≡O 1.148(9) A.
