1353093-85-2Relevant academic research and scientific papers
N-heterocyclic carbene catalyzed C-glycosylation: A concise approach from stetter reaction
Vedachalam, Seenuvasan,Tan, Shi Min,Teo, Hui Ping,Cai, Shuting,Liu, Xue-Wei
supporting information; experimental part, p. 174 - 177 (2012/02/16)
Described herein is the first example of an organocatalytic approach for acylanion addition to the anomeric carbon of 2-nitroglucal using an N-heterocyclic carbene catalyst. Control over the reaction conditions gives β-selective and nitro-eliminated C-glycosides, providing opportunities to produce new classes of C-glycoside.
