1353585-13-3Relevant academic research and scientific papers
Catalytic hydroboration by an imido-hydrido complex of Mo(iv)
Khalimon, Andrey Y.,Farha, Philip,Kuzmina, Lyudmila G.,Nikonov, Georgii I.
, p. 455 - 457 (2012)
The imido-hydrido complex (ArN)Mo(H)(Cl)(PMe3)3 catalyses a variety of hydroboration reactions, including the first example of catalytic addition of HBCat to nitriles to form the bis(borylated) amines RCH2N(BCat)2/su
Imido-hydrido complexes of Mo(IV): Catalysis and mechanistic aspects of hydroboration reactions
Khalimon, Andrey Y.,Farha, Philip M.,Nikonov, Georgii I.
supporting information, p. 18945 - 18956 (2015/11/11)
Imido-hydrido complexes (ArN)Mo(H)(Cl)(PMe3)3 (1) and (ArN)Mo(H)2(PMe3)3 (2) (Ar = 2,6-diisopropylphenyl) catalyse a variety of hydroboration reactions, including the rare examples of addition of HBCat to nitriles to form bis(borylated) amines RCH2N(BCat)2. Stoichiometric reactivity of complexes 1 and 2 with nitriles and HBCat suggest that catalytic reactions proceed via a series of agostic borylamido and borylamino complexes. For complex 1, catalysis starts with addition of nitriles across the Mo-H bond to give (ArN)Mo(Cl)(NCHR)(PMe3)2; whereas for complex 2 stoichiometric reactions suggest initial addition of HBCat to form the agostic complex Mo(H)2(PMe3)3(η3-NAr-HBcat) (16).
